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Question

For a metal of work function $6.6 \text{ eV}$, which of the following wavelengths of incident radiation does not give rise to the photoelectric effect?
(Take Planck's constant as $6.6 \times 10^{-34} \text{ J s}$)

The correct answer is
$200 \text{ nm}$

Understanding the Photoelectric Effect Condition

The photoelectric effect happens only if the energy of the incident photon ($E_{photon}$) meets or exceeds the metal's work function ($\phi$).

Photon energy is calculated using $E_{photon} = \frac{hc}{\lambda}$, where $h$ is Planck's constant, $c$ is the speed of light, and $\lambda$ is the wavelength.

The condition for the effect is: $ \frac{hc}{\lambda} \ge \phi $ This means the effect occurs for wavelengths $\lambda \le \frac{hc}{\phi}$.

Conversely, the effect *does not* occur if the photon energy is less than the work function: $ \frac{hc}{\lambda} < \phi $ This condition implies the effect is absent for wavelengths $\lambda > \frac{hc}{\phi}$. The critical wavelength $\lambda_0 = \frac{hc}{\phi}$ is known as the threshold wavelength.

Calculating the Threshold Wavelength

We are given:

  • Work function, $\phi = 6.6 \text{ eV}$
  • Planck's constant, $h = 6.6 \times 10^{-34} \text{ J s}$
  • Speed of light, $c \approx 3 \times 10^8 \text{ m/s}$
  • Conversion factor, $1 \text{ eV} \approx 1.602 \times 10^{-19} \text{ J}$

First, calculate the value of $hc$:

$ hc = (6.6 \times 10^{-34} \text{ J s}) \times (3 \times 10^8 \text{ m/s}) = 1.98 \times 10^{-25} \text{ J m} $

Next, convert the work function $\phi$ from electron volts (eV) to Joules (J):

$ \phi = 6.6 \text{ eV} \times (1.602 \times 10^{-19} \text{ J/eV}) \approx 1.05732 \times 10^{-18} \text{ J} $

Now, calculate the threshold wavelength $\lambda_0$ using the formula $\lambda_0 = \frac{hc}{\phi}$:

$ \lambda_0 = \frac{1.98 \times 10^{-25} \text{ J m}}{1.05732 \times 10^{-18} \text{ J}} \approx 1.8726 \times 10^{-7} \text{ m} $

Convert this threshold wavelength to nanometers (nm):

$ \lambda_0 \approx 1.8726 \times 10^{-7} \text{ m} \times \frac{10^9 \text{ nm}}{1 \text{ m}} \approx 187.3 \text{ nm} $

Identifying the Wavelength Without Photoelectric Effect

The photoelectric effect will not occur for incident radiation wavelengths ($\lambda$) that are greater than the threshold wavelength ($\lambda_0$).

We need to find the option where $\lambda > 187.3 \text{ nm}$. Let's check the given options:

  • Option 1: $50 \text{ nm}$ ($50 < 187.3$) - Effect occurs.
  • Option 2: $100 \text{ nm}$ ($100 < 187.3$) - Effect occurs.
  • Option 3: $150 \text{ nm}$ ($150 < 187.3$) - Effect occurs.
  • Option 4: $200 \text{ nm}$ ($200 > 187.3$) - Effect does NOT occur.

Therefore, the wavelength of incident radiation that does not give rise to the photoelectric effect is $200 \text{ nm}$.

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