Which of the following oxidising agent is used to convert ethanol to ethanal?
\(\mathrm{CrO_3}\) in anhydrous medium
Strong oxidising agents such as acidified/alkaline \(\mathrm{KMnO_4}\) and acidified \(\mathrm{K_2Cr_2O_7}\) oxidise a primary alcohol all the way to the carboxylic acid.
To stop at the aldehyde stage, a mild reagent in anhydrous medium is used: \(\mathrm{CrO_3}\) (anhydrous, e.g. Collins reagent) or PCC.
\(\mathrm{CH_3CH_2OH \xrightarrow{CrO_3\ (anhydrous)} CH_3CHO}\)
Hence, \(\mathrm{CrO_3}\) in anhydrous medium.
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Important Questions from Organic Chemistry
- In Dumas method for estimation of nitrogen, 0.50 g of an organic compound gave 70 mL of nitrogen collected at 300 K and 715 mm pressure. The percentage of nitrogen in the organic compound is ______ %.
(Aqueous tension at 300 K is 15 mm). - $0.25 \text{ g}$ of an organic compound "A" containing carbon, hydrogen and oxygen was analysed using the combustion method. There was an increase in mass of $\text{CaCl}_2$ tube and potash tube at the end of the experiment. The amount was found to be $0.15 \text{ g}$ and $0.1837 \text{ g}$, respectively. The percentage of oxygen in compound A is ______ %. (Nearest integer)
(Given: molar mass in $\text{g mol}^{-1}$ $\text{H} : 1, \text{C} : 12, \text{O} : 16$) - Grignard reagent $\text{RMgBr (P)}$ reacts with water and forms a gas $\text{(Q)}$. One gram of Q occupies $1.4 \text{ dm}^3$ at STP. (P) on reaction with dry ice in dry ether followed by $\text{H}_3\text{O}^+$ forms a compound $\text{(Z)}$. 0.1 mole of $\text{(Z)}$ will weigh _________ g. (Nearest integer)
- Consider all the structural isomers with molecular formula $\text{C}_5\text{H}_{11}\text{Br}$ are separately treated with $\text{KOH(aq)}$ to give respective substitution products, without any rearrangement. The number of products which can exhibit optical isomerism from these is ___________.
The major products U and V in the following reaction are
