Which of the following is used in the production of freon refrigerant R-22?
\(\mathrm{CHCl_3}\)
Freon R-22 is chlorodifluoromethane, \(\mathrm{CHClF_2}\), a one-carbon compound with one hydrogen.
It is made by partial fluorination of chloroform with HF (Swarts-type exchange, catalysed by \(\mathrm{SbCl_5}\)):
\(\mathrm{CHCl_3+2HF\rightarrow CHClF_2+2HCl}\)
A major use of chloroform is therefore in the production of the freon refrigerant R-22.
Hence, \(\mathrm{CHCl_3}\).
The carbohydrates are stored in animal body as
Oxidation of gluconic acid with nitric acid gives
An aromatic compound (X) of molecular formula, \(\mathrm{C_7H_7Cl}\), on ammonolysis gives Y (Molecular formula, \(\mathrm{C_7H_9N}\)). The compound ‘Y’ reacts with two moles of \(\mathrm{CH_3Cl}\) gives N, N-Dimethylphenylmethanamine. The compounds ‘X’ and ‘Y’ are
The order of boiling point of the following amines is
(i) Butan-1-amine (ii) N-Ethylethanamine (iii) N,N-Dimethylethanamine
The number of moles of alkyl halides required to convert primary amine into quaternary ammonium salt is
Match the following
| Compound | use |
| (a) Benzaldehyde | (i) food preservative |
| (b) Methanoic acid | (ii) nylon 6,6 |
| (c) Sodium benzoate | (iii) perfumery |
| (d) Hexanedioic acid | (iv) Electroplating industry |
When \(\mathrm{C_6H_5CHO}\) reacts with the mixture of \(\mathrm{HNO_3}\) and \(\mathrm{H_2SO_4}\) at 273-283K gives
When benzene is treated with carbon monoxide and hydrogen chloride in the presence of anhydrous aluminium chloride, benzaldehyde is formed. The reaction is known as
The order of acidity of the following compounds is
(i) \(o\)-Nitrophenol (ii) Phenol (iii) \(o\)-Cresol (iv) Ethanol
The reagent used for the conversion of carboxylic acids to primary alcohols is
The major products U and V in the following reaction are
