For a certain reaction R $\rightarrow$ Product, the plot of [R] vs time has a negative slope as shown. The order of reaction is :
0
To determine the order of the reaction, we need to analyze the given plot of [R] (concentration of reactant) versus time.
The plot shows a linear decrease in the concentration of R with time, indicating a constant rate of reaction regardless of the concentration of R.
Conclusion: The order of the reaction is 0 (zero-order reaction).
This option is justified as the plot supports the characteristic behavior of a zero-order reaction where the concentration of the reactant decreases linearly with time.
| List I (Order of reaction) | List II (Unit of rate constant) |
| A. Zero order | I. $mol^{-1} L s^{-1}$ |
| B. First order | II. $mol^{-2} L^2 s^{-1}$ |
| C. Second order | III. $s^{-1}$ |
| D. Third order | IV. $mol L^{-1} s^{-1}$ |
Consider the following reaction :
$2A (g) + B (g) \rightarrow 2D (g)$
$\Delta U^\ominus = -10 \text{ kJ mol}^{-1}$ and $\Delta S^\ominus = -44 \text{ J K}^{-1}$ at 298 K.
Identify the correct option with $\Delta G^\ominus$ for the reaction and spontaneity of the reaction at 298 K. (Given : $R = 8.31 \text{ J mol}^{-1} \text{K}^{-1}$)
At 298 K, a certain buffer solution contains equal concentrations of $X^{-}$ and $HX$. $K_b$ for $X^-$ is $10^{-10}$. What is the pH of this buffer solution ?