For a certain reaction R $\rightarrow$ Product, the plot of [R] vs time has a negative slope as shown. The order of reaction is :
0
To determine the order of the reaction, we need to analyze the given plot of [R] (concentration of reactant) versus time.
The plot shows a linear decrease in the concentration of R with time, indicating a constant rate of reaction regardless of the concentration of R.
Conclusion: The order of the reaction is 0 (zero-order reaction).
This option is justified as the plot supports the characteristic behavior of a zero-order reaction where the concentration of the reactant decreases linearly with time.
| List I (Order of reaction) | List II (Unit of rate constant) |
| A. Zero order | I. $mol^{-1} L s^{-1}$ |
| B. First order | II. $mol^{-2} L^2 s^{-1}$ |
| C. Second order | III. $s^{-1}$ |
| D. Third order | IV. $mol L^{-1} s^{-1}$ |
Calculate emf of the half cell given below :
$$Pt(s) | H_2 (g, 2 \text{ atm}) | HCl (aq, 0.02 \text{ M})$$
$$E_{H_2 /H^+}^\circ = 0 \text{ V}$$
(Given : $\frac{2.303 RT}{F} = 0.059$, $\log 2 = 0.3010$)
At 298 K, a certain buffer solution contains equal concentrations of $X^{-}$ and $HX$. $K_b$ for $X^-$ is $10^{-10}$. What is the pH of this buffer solution ?