This question relates to the First Law of Thermodynamics, which describes the conservation of energy. The law states that the change in internal energy ($\Delta U$) of a system is equal to the heat added to the system ($Q$) minus the work done by the system ($W$).
The formula for the First Law of Thermodynamics is:
$ \Delta U = Q - W $
Substitute the given values into the First Law equation:
$ \Delta U = 500 \text{ J} - 200 \text{ J} $
$ \Delta U = 300 \text{ J} $
Therefore, the change in internal energy of the system is 300 J.
For a certain reaction R $\rightarrow$ Product, the plot of [R] vs time has a negative slope as shown. The order of reaction is :

| List I (Order of reaction) | List II (Unit of rate constant) |
| A. Zero order | I. $mol^{-1} L s^{-1}$ |
| B. First order | II. $mol^{-2} L^2 s^{-1}$ |
| C. Second order | III. $s^{-1}$ |
| D. Third order | IV. $mol L^{-1} s^{-1}$ |
Calculate emf of the half cell given below :
$$Pt(s) | H_2 (g, 2 \text{ atm}) | HCl (aq, 0.02 \text{ M})$$
$$E_{H_2 /H^+}^\circ = 0 \text{ V}$$
(Given : $\frac{2.303 RT}{F} = 0.059$, $\log 2 = 0.3010$)
At 298 K, a certain buffer solution contains equal concentrations of $X^{-}$ and $HX$. $K_b$ for $X^-$ is $10^{-10}$. What is the pH of this buffer solution ?