The number of microstates of distributing five quanta of energy among four distinguishable particles is :
56
This is a counting problem of the "stars and bars" type. The quanta of energy are indistinguishable from one another — one quantum is the same as any other — while the particles are distinguishable, so it matters which particle receives how many.
The standard result for distributing \(q\) identical quanta among \(N\) distinguishable particles is
\(W = \binom{q + N - 1}{q} = \frac{(q+N-1)!}{q!\,(N-1)!}\).
The reasoning behind it: lay out the \(q\) quanta in a row and insert \(N-1\) dividers to split them among the \(N\) particles. Each distinct arrangement of quanta and dividers is one microstate, and there are \(q + N - 1\) positions of which we choose \(q\) for the quanta.
Substitute \(q = 5\) and \(N = 4\):
\(W = \binom{5 + 4 - 1}{5} = \binom{8}{5} = \frac{8!}{5!\,3!} = \frac{8 \times 7 \times 6}{3 \times 2 \times 1} = 56\).
Note that \(\binom{8}{5} = \binom{8}{3}\), so the same answer follows from choosing the positions of the three dividers instead — a useful check.
The value 126 is \(\binom{9}{4}\), obtained by miscounting the number of dividers, and 35 is \(\binom{7}{3}\). The quantity \(W\) computed this way is exactly the statistical weight that enters the Boltzmann entropy \(S = k\ln W\).
Hence the number of microstates is 56.
The property measured in derivative thermogravimetric analysis (DTG) is :
Analysis of four different samples of an alloy yielded 12.12, 12.14, 12.10 and 12.22% of metal. The mean deviation of the result is :
For the first order consecutive reaction :

Which of the following statement is incorrect ?
A given reaction is fitted into the following Arrhenius form :
K2 = 6.0 × 1014 (S-1) . exp \(\left[-\frac{104.4\ (\mathrm{kJ\,mol^{-1}})}{RT}\right]\)
Value of the rate constant at very high temperature would be :
The following half cell represents, normal hydrogen electrode (NHE) :
If, we discharge the electrochemical cell rapidly, then :
E° value for various ions are as follows :
E°(MnO4-) = +1.51 V
E°(Ag/Ag+) = +0.7996 V
E°(Au/Au+) = +1.692 V
E°(Zn/Zn2+) = -0.761 V
Based on this data, permaganate can be used to oxidize :
Vapour pressure of 0.5 molal solution of non-volatile solute in organic solvent at 30°C would be :
(Given : vapour pressure of pure organic solvent is 100 torr; the molecular weight of organic solvent is 100 g mol-1).
Molar conductance of 0.01 M acetic acid was found to be 16 × 10-4 S m2 mol-1 at 30°C. Molar conductance of H+ and CH3COO- ions at infinite dilution are 350 × 10-4 S m2 mol-1 and 50 × 10-4 S m2 mol-1, respectively at same temperature. What percentage of acetic acid is dissociated at that concentration ?
The variation of Cp with pressure at constant temperature is given by :
Two blocks of ice when pressed together join to form one block because
The ratio C p/C vof the specific heats at constant pressure and volume of a monoatomic ideal gas in two dimensions is
The total number of phonon modes in a solid of volume V is \(\int_{\rm{0}}^{{\rm{ω_ D}}} {{\rm{g}}\left( {\rm{ω }} \right)\,} {\rm{dω }}\) = 3N, where N is the number of primitive cells, ω Dis the Debye frequency and density of photon modes is g( ω ) = AV ω2 (with A > 0 a constant). If the density of the solid doubles in a phase transition, the Debye temperature θ D, will
The dispersion relation of a gas of non-interacting bosons in d dimensions is E(k) = ak s, where a and s are positive constants. Bose-Einstein condensation will occur for all values of
Example of thermoplastic among the following is