The number of microstates of distributing five quanta of energy among four distinguishable particles is :
56
This is a counting problem of the "stars and bars" type. The quanta of energy are indistinguishable from one another — one quantum is the same as any other — while the particles are distinguishable, so it matters which particle receives how many.
The standard result for distributing \(q\) identical quanta among \(N\) distinguishable particles is
\(W = \binom{q + N - 1}{q} = \frac{(q+N-1)!}{q!\,(N-1)!}\).
The reasoning behind it: lay out the \(q\) quanta in a row and insert \(N-1\) dividers to split them among the \(N\) particles. Each distinct arrangement of quanta and dividers is one microstate, and there are \(q + N - 1\) positions of which we choose \(q\) for the quanta.
Substitute \(q = 5\) and \(N = 4\):
\(W = \binom{5 + 4 - 1}{5} = \binom{8}{5} = \frac{8!}{5!\,3!} = \frac{8 \times 7 \times 6}{3 \times 2 \times 1} = 56\).
Note that \(\binom{8}{5} = \binom{8}{3}\), so the same answer follows from choosing the positions of the three dividers instead — a useful check.
The value 126 is \(\binom{9}{4}\), obtained by miscounting the number of dividers, and 35 is \(\binom{7}{3}\). The quantity \(W\) computed this way is exactly the statistical weight that enters the Boltzmann entropy \(S = k\ln W\).
Hence the number of microstates is 56.
The property measured in derivative thermogravimetric analysis (DTG) is :
Analysis of four different samples of an alloy yielded 12.12, 12.14, 12.10 and 12.22% of metal. The mean deviation of the result is :
For the first order consecutive reaction :

Which of the following statement is incorrect ?
A given reaction is fitted into the following Arrhenius form :
K2 = 6.0 × 1014 (S-1) . exp \(\left[-\frac{104.4\ (\mathrm{kJ\,mol^{-1}})}{RT}\right]\)
Value of the rate constant at very high temperature would be :
E° value for various ions are as follows :
E°(MnO4-) = +1.51 V
E°(Ag/Ag+) = +0.7996 V
E°(Au/Au+) = +1.692 V
E°(Zn/Zn2+) = -0.761 V
Based on this data, permaganate can be used to oxidize :
Vapour pressure of 0.5 molal solution of non-volatile solute in organic solvent at 30°C would be :
(Given : vapour pressure of pure organic solvent is 100 torr; the molecular weight of organic solvent is 100 g mol-1).
The following half cell represents, normal hydrogen electrode (NHE) :
If, we discharge the electrochemical cell rapidly, then :
Consider the reaction :
H2S(g) + \(\tfrac{3}{2}\) O2(g) → SO2(g) + H2O(g), ΔH° = 518.62 kJ
What is the effect of increase of temperature and pressure on the reaction ?
The variation of Cp with pressure at constant temperature is given by :
Choose the Incorrect Statement:
1 For a system at equilibrium, chemical potential is same in all phases.
2 Gibb's free energy change is zero at equilibrium state of a system.
3 Gibb's free energy change is positive for reaction to occur spontaneously.
4 $\Delta G$ will become more negative with increasing temperature.
Melting Point of pure ice is-
Which one among the following statements with reference to the properties of water is not correct?