Analysis of four different samples of an alloy yielded 12.12, 12.14, 12.10 and 12.22% of metal. The mean deviation of the result is :
0.0375
Mean deviation is the average of the absolute deviations from the mean, so the calculation has three steps.
Step 1 — find the mean. \(\bar{x} = \frac{12.12 + 12.14 + 12.10 + 12.22}{4} = \frac{48.58}{4} = 12.145\)%.
Step 2 — take the absolute deviation of each reading.
\(|12.12 - 12.145| = 0.025\); \(|12.14 - 12.145| = 0.005\); \(|12.10 - 12.145| = 0.045\); \(|12.22 - 12.145| = 0.075\).
Step 3 — average those deviations. \(\text{mean deviation} = \frac{0.025 + 0.005 + 0.045 + 0.075}{4} = \frac{0.150}{4} = 0.0375\).
Two checks are worth making. The answer must be positive, because absolute values are used — a negative figure could only arise from forgetting the modulus, and the signed deviations always sum to zero. And it must be smaller than the largest single deviation (0.075), since it is an average of values including much smaller ones.
The value 0.1500 is the sum of the deviations rather than their mean, so it is the result of omitting the final division by four.
Hence the mean deviation is 0.0375.
The property measured in derivative thermogravimetric analysis (DTG) is :
For the first order consecutive reaction :

Which of the following statement is incorrect ?
A given reaction is fitted into the following Arrhenius form :
K2 = 6.0 × 1014 (S-1) . exp \(\left[-\frac{104.4\ (\mathrm{kJ\,mol^{-1}})}{RT}\right]\)
Value of the rate constant at very high temperature would be :
The following half cell represents, normal hydrogen electrode (NHE) :
If, we discharge the electrochemical cell rapidly, then :
E° value for various ions are as follows :
E°(MnO4-) = +1.51 V
E°(Ag/Ag+) = +0.7996 V
E°(Au/Au+) = +1.692 V
E°(Zn/Zn2+) = -0.761 V
Based on this data, permaganate can be used to oxidize :
Vapour pressure of 0.5 molal solution of non-volatile solute in organic solvent at 30°C would be :
(Given : vapour pressure of pure organic solvent is 100 torr; the molecular weight of organic solvent is 100 g mol-1).
Molar conductance of 0.01 M acetic acid was found to be 16 × 10-4 S m2 mol-1 at 30°C. Molar conductance of H+ and CH3COO- ions at infinite dilution are 350 × 10-4 S m2 mol-1 and 50 × 10-4 S m2 mol-1, respectively at same temperature. What percentage of acetic acid is dissociated at that concentration ?
The variation of Cp with pressure at constant temperature is given by :
Consider the reaction :
H2S(g) + \(\tfrac{3}{2}\) O2(g) → SO2(g) + H2O(g), ΔH° = 518.62 kJ
What is the effect of increase of temperature and pressure on the reaction ?
Two blocks of ice when pressed together join to form one block because
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