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Question

The volume of an ideal gas increases 8 times and temperature becomes $(1/4)^{\text{th}}$ of initial temperature during a reversible change. If there is no exchange of heat in this process ($\Delta Q = 0$) then identify the gas from the following options (Assuming the gases given in the options are ideal gases):

The correct answer is
$\text{CO}_2$

Adiabatic Process Calculation

The process described is a reversible change with no heat exchange ($\Delta Q = 0$). This signifies an adiabatic process for the ideal gas.

Adiabatic Process Formula

The relationship between temperature ($T$) and volume ($V$) during an adiabatic process for an ideal gas is:

$ T V^{\gamma-1} = \text{constant} $

Here, $\gamma$ represents the adiabatic index, which depends on the gas type.

Applying Given Conditions

Let the initial state be (1) and the final state be (2). The formula can be written as:

$ T_1 V_1^{\gamma-1} = T_2 V_2^{\gamma-1} $

The problem states:

  • Volume increases 8 times: $V_2 = 8V_1$
  • Temperature becomes 1/4th: $T_2 = \frac{1}{4} T_1$

Calculating the Adiabatic Index ($\gamma$)

Substitute the given values into the adiabatic equation:

$ T_1 V_1^{\gamma-1} = \left(\frac{1}{4} T_1\right) (8V_1)^{\gamma-1} $

Divide both sides by $T_1$:

$ V_1^{\gamma-1} = \frac{1}{4} (8V_1)^{\gamma-1} $

Rearrange to isolate the volume terms:

$ 4 = \frac{(8V_1)^{\gamma-1}}{V_1^{\gamma-1}} $

Simplify using exponent rules:

$ 4 = \left(\frac{8V_1}{V_1}\right)^{\gamma-1} $

$ 4 = 8^{\gamma-1} $

Express both sides with the base 2:

$ 2^2 = (2^3)^{\gamma-1} $

$ 2^2 = 2^{3(\gamma-1)} $

Equate the exponents:

$ 2 = 3(\gamma-1) $

Solve for $\gamma$:

$ \gamma-1 = \frac{2}{3} $

$ \gamma = 1 + \frac{2}{3} = \frac{5}{3} $

Identifying the Gas

The calculated adiabatic index is $\gamma = 5/3$. This value is characteristic of monatomic ideal gases.

From the given options, He (Helium) is a monatomic gas.

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Similar Questions

  1. Which of the following best represents the temperature versus heat supplied graph for water, in the range of $-20^\circ\text{C}$ to $120^\circ\text{C}$ ?
  2. $10 \text{ kg}$ of ice at $-10^\circ\text{C}$ is added to $100 \text{ kg}$ of water to lower its temperature from $25^\circ\text{C}$. Consider no heat exchange to surroundings. The decrement to the temperature of water is ________$^\circ\text{C}$.
    (specific heat of ice = $2100 \text{ J/Kg.}^\circ\text{C}$, specific heat of water = $4200 \text{ J/Kg.}^\circ\text{C}$, latent heat of fusion of ice = $3.36 \times 10^5 \text{ J/Kg}$)
  3. Rods x and y of equal dimensions but of different materials are joined as shown in figure. Temperatures of end points $A$ and $F$ are maintained at $100^\circ\text{C}$ and $40^\circ\text{C}$ respectively. Given the thermal conductivity of rod x is three times of that of rod y, the temperature at junction points $B$ and $E$ are (close to):

  4. Consider two boxes containing ideal gases A and B such that their temperatures, pressures and number densities are same. The molecular size of A is half of that of B and mass of molecule A is four times that of B. If the collision frequency in gas B is $32 \times 10^{18}$ /s then collision frequency in gas A is _________ /s.
  5. An insulated cylinder of volume $60 \text{ cm}^3$ is filled with a gas at $27^\circ\text{C}$ and 2 atmospheric pressure. Then the gas is compressed making the final volume as $20 \text{ cm}^3$ while allowing the temperature to rise to $77^\circ\text{C}$. The final pressure is _________ atmospheric pressure.
  6. A brass wire of length 2 m and radius 1 mm at $27^\circ\text{C}$ is held taut between two rigid supports. Initially it was cooled to a temperature of $-43^\circ\text{C}$ creating a tension $T$ in the wire. The temperature to which the wire has to be cooled in order to increase the tension in it to $1.4T$, is ______ $^\circ\text{C}$.
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  9. When $300 \text{ J}$ of heat given to an ideal gas with $C_p = \frac{7}{2} R$ its temperature raises from $20^\circ\text{C}$ to $50^\circ\text{C}$ keeping its volume constant. The mass of the gas is (approximately) _______ g. ($R = 8.314 \text{ J/mol.K}$)
  10. An aluminium and steel rods having same lengths and cross-sections are joined to make total length of $120 \text{ cm}$ at $30^\circ\text{C}$. The coefficient of linear expansion of aluminium and steel are $24 \times 10^{-6} /^\circ\text{C}$ and $1.2 \times 10^{-5} /^\circ\text{C}$, respectively. The length of this composite rod when its temperature is raised to $100^\circ\text{C}$, is ____________ $\text{cm}$.

Important Questions from Heat and Thermodynamics

  1. Which of the following best represents the temperature versus heat supplied graph for water, in the range of $-20^\circ\text{C}$ to $120^\circ\text{C}$ ?
  2. $10 \text{ kg}$ of ice at $-10^\circ\text{C}$ is added to $100 \text{ kg}$ of water to lower its temperature from $25^\circ\text{C}$. Consider no heat exchange to surroundings. The decrement to the temperature of water is ________$^\circ\text{C}$.
    (specific heat of ice = $2100 \text{ J/Kg.}^\circ\text{C}$, specific heat of water = $4200 \text{ J/Kg.}^\circ\text{C}$, latent heat of fusion of ice = $3.36 \times 10^5 \text{ J/Kg}$)
  3. Rods x and y of equal dimensions but of different materials are joined as shown in figure. Temperatures of end points $A$ and $F$ are maintained at $100^\circ\text{C}$ and $40^\circ\text{C}$ respectively. Given the thermal conductivity of rod x is three times of that of rod y, the temperature at junction points $B$ and $E$ are (close to):

  4. Consider two boxes containing ideal gases A and B such that their temperatures, pressures and number densities are same. The molecular size of A is half of that of B and mass of molecule A is four times that of B. If the collision frequency in gas B is $32 \times 10^{18}$ /s then collision frequency in gas A is _________ /s.
  5. An insulated cylinder of volume $60 \text{ cm}^3$ is filled with a gas at $27^\circ\text{C}$ and 2 atmospheric pressure. Then the gas is compressed making the final volume as $20 \text{ cm}^3$ while allowing the temperature to rise to $77^\circ\text{C}$. The final pressure is _________ atmospheric pressure.
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