Understanding how metals react with water helps classify them. Metals have different reactivity levels based on their position in the reactivity series.
Sodium (Na) and Potassium (K) are alkali metals that react vigorously with cold water.
Calcium (Ca) reacts with cold water, but less intensely. It reacts more readily with hot water.
Aluminium (Al) does not react with cold or hot water under normal conditions. This is due to the formation of a protective, inert aluminium oxide ($Al2O3$) layer on its surface. This layer prevents water from contacting the metal.
While Aluminium reacts with steam at high temperatures ($2Al(s) + 3H2O(g) → Al2O3(s) + 3H2(g)$), it remains passive towards liquid water (cold or hot).