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Question

Question is based on the following passage:

Methyl nitrile is hydrolysed to carboxylic acid in the presence of H+ or OH- as catalyst. An intermediate compound [A] is formed during this reaction.

Which of the following is the correct statement for hybridization of C-atom and number of π bonds in the Carbonyl group?

The correct answer is

Sp², 3σ, 1π

- In a carbonyl group (C=O), the carbon is sp² hybridized. The sp² hybridization of carbon leads to the formation of one σ-bond with the oxygen atom, and another σ-bond with the other substituent (such as hydrogen or another carbon). The remaining p-orbitals on carbon and oxygen overlap to form a π bond.

- Thus, the carbon in the carbonyl group has 3 σ bonds and 1 π bond.

- The correct answer is (a) Sp², 3σ, 1π.

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Important Questions from Aldehydes, Ketones and Carboxylic Acids

  1. Phenol is brominated in solvent CS₂ at low temperature. The product formed are:

  2. What is not true regarding compound [B]?

    (A) They are higher boiling liquids than aldehydes and ketones due to extensive H bonding

    (B) They are soluble in Benzene

    (C) They produce alkane when heated with soda lime

    (D) Produces CO₂ when treated with NaHCO₃

    Choose the correct answer from the options given below:

  3. What is the product formed in the following reaction sequence?

  4. What will be the product formed when cyclohexanone undergoes Aldol condensation?

  5. Match the chemical conversion in List-I to the appropriate reagent in List-II:

    List-IList-II
    (A) (I) Na2Cr2O7 in presence of H2SO4
    (B) CH3CH2OH → C2H5OC2H5(II) H2SO4 at 443 K
    (C) (III) Zn
    (D) CH3CH2OH → CH2 = CH2(IV) H2SO4 at 413 K

    Choose the correct answer from the options given below:

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