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Question

What is the product formed in the following reaction sequence?

The correct answer is

(c)

Step 1: Free radical bromination (Br2/hv)
- The benzyl position (-CH2CH3) is highly reactive towards radical bromination. - The bromine (Br) replaces one hydrogen from the benzyl carbon, forming **CBr-CH3**. Step 2: Nucleophilic substitution with KCN
- The bromine atom is replaced by a **-CN** (cyanide) group, forming a **benzyl cyanide** intermediate. Step 3: Hydrolysis of -CN with H3O+
- The **-CN** group undergoes hydrolysis in acidic conditions to form a **carboxyl (-COOH) group**. - The final product is **p-nitrophenyl acetic acid (option c)**. Thus, the correct answer is **(c)**.

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Important Questions from Aldehydes, Ketones and Carboxylic Acids

  1. Phenol is brominated in solvent CS₂ at low temperature. The product formed are:

  2. What is not true regarding compound [B]?

    (A) They are higher boiling liquids than aldehydes and ketones due to extensive H bonding

    (B) They are soluble in Benzene

    (C) They produce alkane when heated with soda lime

    (D) Produces CO₂ when treated with NaHCO₃

    Choose the correct answer from the options given below:

  3. Which of the following is the correct statement for hybridization of C-atom and number of π bonds in the Carbonyl group?

  4. What will be the product formed when cyclohexanone undergoes Aldol condensation?

  5. Match the chemical conversion in List-I to the appropriate reagent in List-II:

    List-IList-II
    (A) (I) Na2Cr2O7 in presence of H2SO4
    (B) CH3CH2OH → C2H5OC2H5(II) H2SO4 at 443 K
    (C) (III) Zn
    (D) CH3CH2OH → CH2 = CH2(IV) H2SO4 at 413 K

    Choose the correct answer from the options given below:

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