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Question

Match the chemical conversion in List-I to the appropriate reagent in List-II:

List-IList-II
(A) (I) Na2Cr2O7 in presence of H2SO4
(B) CH3CH2OH → C2H5OC2H5(II) H2SO4 at 443 K
(C) (III) Zn
(D) CH3CH2OH → CH2 = CH2(IV) H2SO4 at 413 K

Choose the correct answer from the options given below:

The correct answer is

(A)-(III), (B)-(IV), (C)-(I), (D)-(II)

Explanation of the solution:
- **(A)** Phenol can be converted to **benzene** using **Zn** (zinc) through reduction. This corresponds to **(III)**.
- **(B)** **Ethanol** reacts with **H2SO4 at 443 K** to undergo **dehydration** and form **ethyl ether** (C2H5OC2H5). This corresponds to **(IV)**.
- **(C)** **Phenol** can undergo **oxidation** using **Na2Cr2O7** in the presence of **H2SO4**, leading to the formation of a **quinone** or other products. This corresponds to **(I)**.
- **(D)** **Ethanol** undergoes **dehydration** with **H2SO4 at 413 K** to form **ethylene** (CH2 = CH2). This corresponds to **(II)**.
Thus, the correct answer is **Option (a)**: (A)-(III), (B)-(IV), (C)-(I), (D)-(II).

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Important Questions from Aldehydes, Ketones and Carboxylic Acids

  1. Phenol is brominated in solvent CS₂ at low temperature. The product formed are:

  2. What is not true regarding compound [B]?

    (A) They are higher boiling liquids than aldehydes and ketones due to extensive H bonding

    (B) They are soluble in Benzene

    (C) They produce alkane when heated with soda lime

    (D) Produces CO₂ when treated with NaHCO₃

    Choose the correct answer from the options given below:

  3. Which of the following is the correct statement for hybridization of C-atom and number of π bonds in the Carbonyl group?

  4. What is the product formed in the following reaction sequence?

  5. What will be the product formed when cyclohexanone undergoes Aldol condensation?

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