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Question

Which of the following is a chemical change?

This question was previously asked in
RRB ALP 2018 CBT 2 Fitter Question Paper (21-Jan-2019) (Shift 3)
The correct answer is

Butter turning rancid

Understanding Chemical vs. Physical Changes

Changes in matter can be broadly classified into two main types: physical changes and chemical changes. Understanding the difference is key to solving this question.

  • Physical Change: A change where the substance's form, appearance, or physical state changes, but its chemical composition remains the same. These changes are often reversible. Examples include melting, freezing, boiling, condensation, sublimation, cutting, bending, and dissolving.
  • Chemical Change: A change where a substance is transformed into a new substance with different chemical properties. This involves the breaking and forming of chemical bonds. These changes are usually irreversible. Examples include burning, rusting, cooking, and decomposition. Evidence of a chemical change might include a change in color, production of gas, formation of a precipitate, release or absorption of heat or light, or a change in odor.

Analyzing the Options

Let's examine each option provided to determine whether it represents a chemical change or a physical change.

  1. Butter turning rancid:

    When butter turns rancid, it develops an unpleasant smell and taste. This is due to chemical reactions, primarily the hydrolysis and oxidation of fats present in the butter. New chemical compounds, such as butyric acid, are formed, which have different properties than the original fats. This change alters the chemical composition of the butter and is generally irreversible. Therefore, this is a chemical change.

  2. Making dry ice from CO<sub>2</sub>:

    Dry ice is the solid form of carbon dioxide ($\text{CO}_2$). Making dry ice from gaseous $\text{CO}_2$ involves cooling the gas to a very low temperature until it solidifies. This process is called deposition (or desublimation). It is a phase change from gas to solid. The chemical composition ($\text{CO}_2$) remains the same, only its physical state changes. This is a physical change.

  3. Heating a platinum wire:

    Heating a platinum wire typically causes it to get hot and possibly glow red or white depending on the temperature. This involves increasing the kinetic energy of the atoms and potentially changing the temperature and emitting light. However, the platinum atoms themselves do not chemically react with each other or with the surrounding air (platinum is very unreactive, especially when just heated). The chemical composition of the platinum wire remains unchanged. This is a physical change.

  4. Magnetization of iron:

    Magnetizing iron involves aligning the magnetic domains within the iron material. This process makes the iron exhibit magnetic properties. However, the iron atoms themselves are not changed into a different substance, and the chemical composition of the iron remains $\text{Fe}$. This change affects the physical property of magnetism but not the chemical identity of the substance. This is a physical change.

Conclusion

Based on the analysis, the only option that involves a change in the chemical composition of the substance, resulting in the formation of new substances with different properties, is butter turning rancid. This is a classic example of a chemical change.

Change Type of Change Explanation
Butter turning rancid Chemical Change Chemical reactions (hydrolysis, oxidation) form new substances.
Making dry ice from $\text{CO}_2$ Physical Change Phase change from gas to solid; $\text{CO}_2$ remains $\text{CO}_2$.
Heating a platinum wire Physical Change Temperature change, possibly light emission; composition remains $\text{Pt}$.
Magnetization of iron Physical Change Alignment of magnetic domains; composition remains $\text{Fe}$.

Revision Table: Chemical vs. Physical Changes

Characteristic Physical Change Chemical Change
Composition Remains the same Changes; new substances formed
Reversibility Often reversible Usually irreversible
Energy Change Minor energy changes (e.g., phase changes) Significant energy changes (released or absorbed)
Properties Physical properties change (shape, state, temp) Chemical properties change (reactivity, flammability)
Evidence No new substances formed Color change, gas production, precipitate, heat/light, odor change

Additional Information on Chemical Changes

Chemical changes are fundamental to chemistry and involve the transformation of reactants into products. They are often represented by chemical equations.

Key aspects of chemical changes:

  • Bond Breaking and Forming: Chemical changes involve the rearrangement of atoms and molecules through the breaking of existing chemical bonds and the formation of new ones.
  • Law of Conservation of Mass: In any chemical change (chemical reaction), the total mass of the reactants is equal to the total mass of the products. Atoms are rearranged, not created or destroyed.
  • Energy Changes: Chemical reactions either release energy (exothermic reactions, like burning) or absorb energy (endothermic reactions, like photosynthesis).
  • Catalysts: Substances called catalysts can speed up a chemical reaction without being consumed in the process.

Examples of chemical changes are everywhere, from digestion in our bodies to the burning of fuel and the ripening of fruit.

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