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Question

Which among the following is produced using ‘Haber Process’?

This question was previously asked in
SSC Stenographer 2018 Previous Year Paper (08-Feb-2019) (Shift 2)
The correct answer is

Ammonia

Understanding the Haber Process for Ammonia Production

The question asks about the chemical process known as the ‘Haber Process’ and which substance is produced using this method. The Haber Process is a cornerstone of industrial chemistry, specifically designed for the large-scale synthesis of a vital compound.

Let's look at the options provided and determine which one is the product of the Haber Process.

What is the Haber Process?

The Haber Process, also known as the Haber-Bosch Process, is an industrial method for producing ammonia from nitrogen gas and hydrogen gas. It was developed by Fritz Haber and Carl Bosch in the early 20th century. This process is incredibly important globally, primarily for producing fertilizers.

The Chemical Reaction

The reaction involved in the Haber Process is a reversible equilibrium reaction:

\(\text{N}_2\text{(g)} + 3\text{H}_2\text{(g)} \rightleftharpoons 2\text{NH}_3\text{(g)}\)

This shows that one molecule of nitrogen gas (\(\text{N}_2\)) reacts with three molecules of hydrogen gas (\(\text{H}_2\)) to produce two molecules of ammonia gas (\(\text{NH}_3\)).

Conditions for the Haber Process

The Haber Process is carried out under specific conditions to favour the production of ammonia:

  • Temperature: High temperatures, typically between 400-450°C, are used. While a lower temperature would favour the exothermic forward reaction according to Le Chatelier's principle, a higher temperature is needed to achieve a reasonable reaction rate.
  • Pressure: High pressures, usually between 150-350 atmospheres (atm), are applied. Higher pressure favours the side with fewer moles of gas (the product side with 2 moles of \(\text{NH}_3\) compared to 4 moles of reactants), pushing the equilibrium towards ammonia production.
  • Catalyst: An iron catalyst (promoted with potassium oxide, aluminium oxide, etc.) is used to speed up the rate of both the forward and reverse reactions, helping the system reach equilibrium faster without being consumed in the process.

Analyzing the Options

Based on the chemical reaction and the purpose of the Haber Process, let's examine the options:

  • Carbon Dioxide (\(\text{CO}_2\)): Carbon dioxide is produced by combustion, respiration, and other processes. It is not synthesized using the Haber Process.
  • Ammonia (\(\text{NH}_3\)): As explained above, ammonia is the primary product of the reaction between nitrogen and hydrogen in the Haber Process.
  • Sulphur dioxide (\(\text{SO}_2\)): Sulphur dioxide is typically produced by burning sulphur or sulphide ores. It is not related to the Haber Process.
  • Ozone (\(\text{O}_3\)): Ozone is an allotrope of oxygen and is formed naturally in the stratosphere or produced synthetically using electrical discharge. It is not produced via the Haber Process.

Therefore, the substance produced using the Haber Process is Ammonia.

Conclusion

The Haber Process is an industrial method specifically designed for the synthesis of ammonia from atmospheric nitrogen and hydrogen. Among the given options, only Ammonia is produced through this process.

Process Main Product Reactants Typical Conditions
Haber Process Ammonia (\(\text{NH}_3\)) Nitrogen (\(\text{N}_2\)), Hydrogen (\(\text{H}_2\)) High Temp (400-450°C), High Pressure (150-350 atm), Iron catalyst
Other Examples (for comparison) Sulphur Dioxide (\(\text{SO}_2\)) Sulphur, Oxygen Burning Sulphur
Carbon Dioxide (\(\text{CO}_2\)) Combustion of carbon compounds Burning fuels
Ozone (\(\text{O}_3\)) Oxygen UV radiation, Electrical discharge

Revision Table: Key Facts about the Haber Process

Aspect Details
What it is Industrial process for synthesizing ammonia
Who developed it Fritz Haber, Carl Bosch
Reactants Nitrogen gas (\(\text{N}_2\)), Hydrogen gas (\(\text{H}_2\))
Product Ammonia gas (\(\text{NH}_3\))
Chemical Equation \(\text{N}_2\text{(g)} + 3\text{H}_2\text{(g)} \rightleftharpoons 2\text{NH}_3\text{(g)}\)
Catalyst Used Iron (Fe), promoted
Temperature Range 400-450°C
Pressure Range 150-350 atm
Primary Use of Product Fertilizers, nitric acid production

Additional Information: Importance of Ammonia

Ammonia produced by the Haber Process is one of the most important chemicals in the world. Its primary use is in the production of fertilizers, which are essential for modern agriculture to feed the global population. Nitrogen is a key nutrient for plant growth, and ammonia-based fertilizers like urea, ammonium nitrate, and ammonium sulphate provide this nitrogen.

Besides fertilizers, ammonia is also used in the production of nitric acid, which is used in explosives and other chemicals. It is also used as a refrigerant and in cleaning products. The efficiency of the Haber Process has had a massive impact on food production capabilities worldwide.

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