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Question

Topaz is a _______ of fluorine and aluminium.

This question was previously asked in
SSC CGL 2020 Tier-II (English) Previous Year Paper (29-Jan-2022)
The correct answer is

silicate

Understanding Topaz Mineral Classification

The question asks about the classification of Topaz based on its chemical composition, specifically mentioning fluorine and aluminium as components. Minerals are classified into groups based on their dominant anion or anionic group.

What is Topaz?

Topaz is a gemstone and a mineral. Its chemical formula is typically given as \( \text{Al}_2\text{SiO}_4{(\text{F,OH})}_2 \). This formula shows that Topaz contains aluminium (\( \text{Al} \)), silicon (\( \text{Si} \)), oxygen (\( \text{O} \)), fluorine (\( \text{F} \)), and hydroxyl groups (\( \text{OH} \)). The presence of silicon and oxygen, particularly in a specific structural arrangement, is key to its classification.

Mineral Classification Explained

Let's look at the options provided and understand the different mineral classifications:

  • Silicates: These are the largest and most important class of minerals. They are characterized by the presence of the silicate anion, which is based on a silicon atom surrounded by four oxygen atoms in a tetrahedral arrangement (\( \text{SiO}_4^{4-} \)). These tetrahedra can link together in various ways (single units, chains, sheets, frameworks) to form different silicate minerals.
  • Sulphates: These minerals contain the sulphate anion (\( \text{SO}_4^{2-} \)) as their main anionic group. Examples include Gypsum and Barite.
  • Phosphates: These minerals contain the phosphate anion (\( \text{PO}_4^{3-} \)) as their main anionic group. An example is Apatite.
  • Carbonates: These minerals contain the carbonate anion (\( \text{CO}_3^{2-} \)) as their main anionic group. Examples include Calcite and Dolomite.

Classifying Topaz based on Composition

Looking at the chemical formula of Topaz, \( \text{Al}_2\text{SiO}_4{(\text{F,OH})}_2 \), we see the presence of silicon (\( \text{Si} \)) and oxygen (\( \text{O} \)) forming an \(\text{SiO}_4\) group within its structure. This fundamental building block, the silicate tetrahedron, is characteristic of silicate minerals. Although Topaz also contains aluminium and fluorine/hydroxyl, the presence and arrangement of the silicon-oxygen group place it firmly within the silicate class of minerals.

Topaz is specifically an example of a Nesosilicate (also known as orthosilicate), which is a type of silicate mineral where the \( \text{SiO}_4^{4-} \) tetrahedra are isolated and linked by cations (like Aluminium in the case of Topaz).

The absence of sulphate (\( \text{SO}_4^{2-} \)), phosphate (\( \text{PO}_4^{3-} \)), or carbonate (\( \text{CO}_3^{2-} \)) groups means that Topaz is not a sulphate, phosphate, or carbonate mineral.

Common Mineral Classes and Key Anion/Anionic Group
Mineral Class Key Anion/Anionic Group Presence in Topaz
Silicate \( \text{SiO}_4^{4-} \) tetrahedron (or linked forms) Yes (\( \text{SiO}_4 \) group is present)
Sulphate \( \text{SO}_4^{2-} \) No
Phosphate \( \text{PO}_4^{3-} \) No
Carbonate \( \text{CO}_3^{2-} \) No

Based on its chemical formula \( \text{Al}_2\text{SiO}_4{(\text{F,OH})}_2 \), Topaz contains the essential silicate unit (\( \text{SiO}_4 \)) and is thus classified as a silicate mineral.

Revision Table: Topaz Mineral Classification

Summary of Topaz Classification Facts
Mineral Name Chemical Formula Highlights Primary Anionic Group Mineral Class
Topaz Contains Al, Si, O, F/OH \( \text{SiO}_4 \) (Silicate group) Silicate

Additional Information on Topaz

Topaz is a relatively hard mineral (8 on the Mohs scale). It crystallizes in the orthorhombic crystal system. Pure topaz is colorless and transparent. However, impurities can give it various colors, including yellow, blue, pink, peach, green, brown, and violet. Blue topaz is the most common color in jewelry today, although naturally blue topaz is rare; most blue topaz is produced by treating colorless or pale material with irradiation and heat. Topaz is often found in igneous rocks like granite and in pegmatites, as well as in hydrothermal veins and alluvial deposits.

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