Discuss in detail the photochemical smog emphasizing its formation, effects and mitigation. Explain the 1999 Gothenburg Protocol.
Photochemical smog is a type of air pollution, often seen as a brown haze, common in sunny, warm, and dry cities with heavy motor vehicle traffic.
Formation: It's a secondary pollutant, formed when primary pollutants like nitrogen oxides (NOx) and volatile organic compounds (VOCs) react in the presence of sunlight. This chemical reaction creates a toxic cocktail of secondary pollutants, including ground-level ozone (O3), peroxyacetyl nitrate (PAN), and aldehydes.
Effects: It has severe health effects, causing respiratory problems, eye irritation, and headaches. It also damages plant life and can degrade materials like rubber and textiles.
Mitigation: The key is to control the emission of primary pollutants (NOx and VOCs) from vehicles and industries by using catalytic converters, promoting public transport, and shifting to cleaner fuels.
The 1999 Gothenburg Protocol is a multi-pollutant protocol designed to abate acidification, eutrophication, and ground-level ozone by setting emission ceilings for sulphur dioxide, NOx, VOCs, and ammonia.
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