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Question

Identify "A" and mention the name of the mechanism through which it is formed:

The correct answer is

C2H5-O-C2H5, SN2

Solution: When ethanol (CH3CH2OH) reacts with concentrated sulfuric acid (H2SO4) under heat, an elimination reaction takes place, forming ethene (CH2=CH2). This is a classic example of dehydration (elimination of water) to form an alkene.

The mechanism involved is elimination, specifically E1 (unimolecular elimination), where a carbocation intermediate is formed, leading to the removal of a proton and the formation of a double bond.

 

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Important Questions from Alcohols, Phenols and Ethers

  1. Which isomerism is shown by the following pairs?

    CH₃CH₂CH₂OH and CH₃CH₂OCH₃

  2. Correct order of boiling points in the following is:

    (A) CH3CHO

    (B) CH3COOH

    (C) CH3CH2OH

    (D) CH3CH3

    (E) CH3CH2Cl

    Choose the correct answer from the options given below:

  3. Identify allylic alcohol:

    (A) CH2= CH–CH2OH

    (B) CH3= CH–CH2OH

    (C)

    (D)

    Choose the correct answer from the options given below:

  4. In Kolbe's reaction, phenol undergoes:

  5. When methyl bromide is treated with sodium tert-butoxide, the compound formed is:

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