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Question

Airbags work on the principle of a chemical reaction triggered by the impact producing a gaseous product that causes a sudden volume change. Which one among the following chemical conversions is responsible for this?

The correct answer is

Sodium azide into nitrogen gas

Understanding the Airbag Chemical Reaction

Airbags are a crucial safety feature in vehicles, designed to protect occupants during a collision. They work by rapidly inflating a fabric bag between the occupant and the vehicle's interior, cushioning the impact.

The rapid inflation of the airbag is triggered by a chemical reaction. When a collision occurs, sensors detect the impact, and this triggers an igniter. The igniter causes a rapid chemical decomposition of a compound stored within the airbag module. This decomposition produces a large volume of gas very quickly, which inflates the airbag.

The Core Chemical Conversion in Airbags

The primary chemical conversion responsible for the rapid production of gas in many airbag systems involves sodium azide.

  • Sodium azide ($\text{NaN}_3$) is a solid compound stored in the airbag.
  • Upon receiving the signal from the crash sensor, an igniter initiates the decomposition reaction.
  • The sodium azide rapidly decomposes into sodium metal ($\text{Na}$) and nitrogen gas ($\text{N}_2$).

The chemical equation for this initial reaction is:

\(2\text{NaN}_3\text{ (s)} \rightarrow 2\text{Na}\text{ (s)} + 3\text{N}_2\text{ (g)}\)

As you can see from the equation, one of the products is nitrogen gas ($\text{N}_2$). Nitrogen gas is inert and harmless in this context. Crucially, this reaction produces a large amount of nitrogen gas almost instantaneously. It's the sudden generation and expansion of this gas that inflates the airbag.

Following this reaction, other chemicals are often included to neutralize the highly reactive sodium metal produced, converting it into safer compounds.

Analyzing the Given Options

Let's evaluate the provided options in the context of the airbag mechanism:

  • Sodium azide into nitrogen gas: This aligns perfectly with the known chemical process in many airbags. The decomposition of sodium azide produces nitrogen gas, causing the rapid volume increase needed for inflation.
  • Solid carbon dioxide into gaseous carbon dioxide: This describes sublimation, a physical change. While it produces gas, it's not the primary rapid chemical reaction used for initial, extremely fast airbag inflation triggered by impact in typical systems.
  • Carbon dioxide into carbon monoxide: This is a chemical reaction, but converting $\text{CO}_2$ to $\text{CO}$ wouldn't produce the necessary rapid volume increase for airbag inflation. Also, carbon monoxide is a toxic gas, which would be undesirable in an airbag.
  • Sudden conversion of gaseous carbon dioxide into carbon monoxide: Similar to the previous option, this reaction doesn't fit the airbag mechanism. The starting material in typical systems is a solid (sodium azide), and the required output is a large volume of inert gas, not toxic carbon monoxide.

Based on this analysis, the conversion of sodium azide into nitrogen gas is the chemical reaction responsible for the sudden volume change that inflates the airbag.

Revision Table: Airbag Components

Component Role in Airbag System
Crash Sensor Detects collision impact and signals the control unit.
Control Unit Receives signal, determines if airbag deployment is needed, and activates the igniter.
Igniter Starts the chemical reaction that produces gas.
Sodium Azide ($\text{NaN}_3$) Main reactant that decomposes to produce nitrogen gas.
Other Oxidizers/Chemicals (e.g., $\text{KNO}_3$, $\text{SiO}_2$) React with sodium metal produced to form safer compounds (like glass).
Airbag Cushion The fabric bag that inflates with gas.

Additional Information: Airbag Safety and Chemistry

While sodium azide decomposition is the core reaction, modern airbag systems include other chemicals for safety and efficiency. For instance:

  • Potassium nitrate ($\text{KNO}_3$) is often added as an oxidizer. It reacts with the sodium metal produced by the $\text{NaN}_3$ decomposition.
  • Silicon dioxide ($\text{SiO}_2$) is also added. It reacts with the products of the sodium-potassium nitrate reaction to form harmless silicate glass.

These secondary reactions ensure that toxic and reactive sodium metal is quickly converted into stable, safe compounds, preventing potential hazards after deployment.

The entire process, from impact detection to full inflation, happens incredibly fast, typically within 20-50 milliseconds, providing protection before the occupant makes forceful contact with the vehicle interior.

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Important Questions from Chemical Reaction

  1. An iron nail dipped in copper sulphate solution turns brown. This is due to which one of the following types of reactions?

  2. Copper sulphate crystals available in the market are blue coloured crystals. By careful heating, they turn to white colour. Which one of the following is responsible for the blue colour?

  3. Which one of the following is the correct reactivity series with water?

  4. Silver artefacts get tarnished in air due to the formation of

  5. Which one of the following is not an example of a redox reaction?
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