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Question

Consider the following reaction:

2HgO \( \stackrel{\Delta}{\longrightarrow} \) 2Hg + O2

The respective state of HgO, Hg and O2 in the above reaction is

This question was previously asked in
NDA I 2023 GAT Previous Year Paper (16-Apr-2023)
The correct answer is Solid, liquid, gas

Understanding Physical States in Chemical Reactions

The question asks us to identify the physical states of the substances involved in the decomposition of Mercury(II) Oxide (\( \text{HgO} \)) upon heating. The reaction is given as:

\( 2\text{HgO} \stackrel{\Delta}{\longrightarrow} 2\text{Hg} + \text{O}_2 \)

In this reaction, Mercury(II) Oxide (\( \text{HgO} \)) is the reactant, and Mercury (\( \text{Hg} \)) and Oxygen (\( \text{O}_2 \)) are the products. We need to determine their respective states under the reaction conditions, which involve heating (\( \Delta \)).

Physical State of Mercury(II) Oxide (HgO)

Mercury(II) Oxide (\( \text{HgO} \)) is a compound formed from mercury and oxygen. At standard temperature and pressure, \( \text{HgO} \) exists as a solid. It is a reddish-orange or yellow crystalline powder.

The \( \Delta \) symbol above the arrow indicates that the reaction occurs when \( \text{HgO} \) is heated. While heating can cause substances to change state (e.g., melt), Mercury(II) Oxide decomposes into mercury and oxygen at temperatures below its melting point. Therefore, it is typically considered to be in the solid state when the decomposition begins.

  • HgO: Solid state

Physical State of Mercury (Hg)

Mercury (\( \text{Hg} \)) is a chemical element, specifically a metal. Mercury is unique among metals because it is a liquid at room temperature and standard atmospheric pressure. This is a well-known property of mercury.

The reaction produces elemental mercury. Even though the reaction involves heating, the product mercury is formed and exists in its stable liquid state at the temperatures typically associated with this decomposition.

  • Hg: Liquid state

Physical State of Oxygen (O₂)

Oxygen (\( \text{O}_2 \)) is a diatomic molecule and a chemical element. Oxygen is a gas at standard temperature and pressure.

In the decomposition of \( \text{HgO} \), oxygen is released as a gas. The gaseous state is indicated by \( \text{O}_2 \).

  • O₂: Gas state

Summarizing the States

Based on the properties of the substances involved and the reaction conditions, the states are:

  • Reactant \( \text{HgO} \): Solid
  • Product \( \text{Hg} \): Liquid
  • Product \( \text{O}_2 \): Gas

So, the respective states of \( \text{HgO} \), \( \text{Hg} \) and \( \text{O}_2 \) in the reaction are Solid, Liquid, and Gas.

Comparing with Options

Let's compare our findings with the given options:

  • Option 1: Liquid, solid, gas (Incorrect - \( \text{HgO} \) is solid, \( \text{Hg} \) is liquid)
  • Option 2: Solid, solid, gas (Incorrect - \( \text{Hg} \) is liquid)
  • Option 3: Liquid, solid, liquid (Incorrect - \( \text{HgO} \) is solid, \( \text{Hg} \) is liquid, \( \text{O}_2 \) is gas)
  • Option 4: Solid, liquid, gas (Correct - Matches our analysis)

Therefore, the correct option is Solid, liquid, gas.

Revision Table: Common Physical States

Substance Type Typical State at Room Temp (25°C) & 1 atm Example
Ionic Compounds Solid NaCl (Sodium Chloride)
Most Metals Solid (except Mercury) Fe (Iron), Cu (Copper)
Mercury (Hg) Liquid Hg (Mercury)
Non-metal elements (e.g., O₂, N₂, H₂, Cl₂, F₂, Noble Gases) Gas O₂ (Oxygen), N₂ (Nitrogen)
Some Non-metal elements (e.g., Br₂, I₂) Liquid (Br₂), Solid (I₂) Br₂ (Bromine), I₂ (Iodine)
Water (H₂O) Liquid H₂O (Water)

Additional Information on Chemical Reactions and States

Chemical equations often include symbols in parentheses after each chemical formula to indicate the physical state of the substance:

  • (s) for solid
  • (l) for liquid
  • (g) for gas
  • (aq) for aqueous solution (dissolved in water)

The decomposition of \( \text{HgO} \) could be written more formally as:

\( 2\text{HgO (s)} \stackrel{\Delta}{\longrightarrow} 2\text{Hg (l)} + \text{O}_2 \text{(g)} \)

This notation explicitly shows the states of matter involved in the reaction under the given conditions. Understanding the common states of different types of substances (elements, ionic compounds, molecular compounds) is crucial for interpreting chemical reactions.

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Similar Questions

  1. Directions: The following items consist of two statements, Statement I and Statement II. You are to examine these two statements carefully and select the answers to these items using the code given below:

    Statement I:  Oxygen gas is easily produced at a faster rate by heating a mixture of Potassium Chlorate and Manganese dioxide than heating Potassium chlorate alone.

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Important Questions from Chemical Reaction

  1. Which of the following statement is/are true?

    I. In physical change new substance is formed. substance is formed.

    II. In chemical change no new substance is formed.

  2. Which of the following cells involves similar chemical reactions?

  3. The information not obtained from balanced chemical equation is

  4. Oxygen cannot be obtained by which one of the following methods?

  5. Which of the following statement is correct?

    I. Insoluble salt is obtained by precipitation reaction.

    II. Addition of oxygen or loss of hydrogen is called oxidation.

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