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Question

What is the oxidation state of Vanadium in V2O5?

This question was previously asked in
NDA 2 2024 GAT Question Paper (01-Sep-2024)
The correct answer is +5

Understanding Oxidation States in Chemical Compounds

The question asks us to determine the oxidation state of Vanadium (V) in the compound V2O5. The oxidation state, also known as the oxidation number, represents the hypothetical charge an atom would have if all bonds to atoms of different elements were 100% ionic.

To find the oxidation state of an element in a neutral compound like V2O5, we use the following principle: the sum of the oxidation states of all atoms in a neutral compound is zero.

Calculating the Oxidation State of Vanadium in V2O5

Let's calculate the oxidation state of Vanadium (V) in V2O5 step-by-step:

  • We know the usual oxidation state of Oxygen (O) in most compounds is -2.
  • Let 'x' be the oxidation state of Vanadium (V) that we want to find.
  • The compound V2O5 contains 2 Vanadium atoms and 5 Oxygen atoms.
  • The sum of the oxidation states of all atoms in V2O5 is zero because it is a neutral compound.

We can set up an equation based on this information:

\( (2 \times \text{Oxidation state of V}) + (5 \times \text{Oxidation state of O}) = 0 \)

Substitute the known values into the equation:

\( (2 \times x) + (5 \times -2) = 0 \)

\( 2x - 10 = 0 \)

Now, solve for 'x':

\( 2x = 10 \)

\( x = \frac{10}{2} \)

\( x = +5 \)

Therefore, the oxidation state of Vanadium in V2O5 is +5.

Explanation of the Result

The calculation shows that each Vanadium atom in V2O5 has an oxidation state of +5. This is consistent with Vanadium being a transition metal, which can exhibit multiple oxidation states.

Revision Table: Key Oxidation State Rules

Element or IonCommon Oxidation StateNotes
Oxygen (O)-2Except in peroxides (-1), superoxides (-1/2), and compounds with fluorine (e.g., OF2, +2).
Hydrogen (H)+1Except in metal hydrides (e.g., NaH, -1).
Alkali Metals (Group 1)+1Always in compounds.
Alkaline Earth Metals (Group 2)+2Always in compounds.
Halogens (Group 17)-1Usually, but can be positive when bonded to more electronegative elements (like Oxygen).
Sum of Oxidation States0For a neutral compound.
Sum of Oxidation StatesCharge of the ionFor a polyatomic ion.

Additional Information: Vanadium Compounds and Oxidation States

Vanadium is a transition metal with atomic number 23. It is known for forming compounds with a variety of oxidation states, including +2, +3, +4, and +5. V2O5, where Vanadium is in the +5 oxidation state, is one of its most stable compounds and is commonly used as a catalyst in industrial processes, such as the contact process for sulfuric acid production.

Examples of other Vanadium compounds and their oxidation states:

  • VO (Vanadium(II) oxide): Vanadium has an oxidation state of +2.
  • V2O3 (Vanadium(III) oxide): Vanadium has an oxidation state of +3.
  • VO2 (Vanadium(IV) oxide): Vanadium has an oxidation state of +4.
  • VCl3 (Vanadium(III) chloride): Vanadium has an oxidation state of +3.

Understanding how to calculate oxidation states is fundamental in chemistry for naming compounds, predicting chemical reactions, and understanding redox processes.

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