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Question

Which one of the following polymers does not contain glucose units?

This question was previously asked in
CDS I 2017 General Knowledge Previous Year Paper (05-Feb-2017)
The correct answer is

Rubber

Identifying Polymers Without Glucose Units

The question asks us to identify which of the given polymers is not composed of glucose units. Glucose is a simple sugar (monosaccharide) that serves as a building block for many complex carbohydrates (polysaccharides).

Analyzing the Options

Let's examine the composition of each polymer listed:

  • Glycogen: Glycogen is a highly branched polysaccharide that serves as the primary storage form of glucose in animals and fungi. It is entirely composed of glucose units linked together by glycosidic bonds.
  • Starch: Starch is the main carbohydrate storage in plants. It is a polysaccharide made up of glucose units. Starch consists of two types of molecules: amylose (a linear polymer of glucose) and amylopectin (a branched polymer of glucose). Both are constructed from glucose monomers.
  • Cellulose: Cellulose is a linear polysaccharide found in the cell walls of plants. It is the most abundant organic polymer on Earth. Cellulose is also composed solely of glucose units linked together, but the linkage type is different from that in starch and glycogen, making it difficult for most animals to digest.
  • Rubber: Natural rubber is an elastomer, which is a type of polymer. It is primarily composed of polyisoprene. The monomer unit of polyisoprene is isoprene (\(\text{C}_5\text{H}_8\)), not glucose (\(\text{C}_6\text{H}_{12}\text{O}_6\)). Therefore, rubber does not contain glucose units as its building blocks.

Based on the composition of each polymer, it is clear that glycogen, starch, and cellulose are all polysaccharides made up of glucose units. Rubber, on the other hand, is a polymer made from isoprene units.

Composition of Polymers
Polymer Building Block (Monomer) Contains Glucose Units?
Glycogen Glucose Yes
Starch Glucose Yes
Cellulose Glucose Yes
Rubber Isoprene No

Conclusion

Among the given options, rubber is the only polymer that does not have glucose units as its monomer or building block. It is formed from isoprene units polymerization.

Revision Table: Polymers and Monomers

Key Polymers and Their Monomers
Polymer Type Examples Typical Monomer(s)
Polysaccharides Starch, Glycogen, Cellulose, Chitin Monosaccharides (like glucose, fructose, galactose, N-acetylglucosamine)
Proteins Enzymes, Antibodies Amino Acids
Nucleic Acids DNA, RNA Nucleotides
Elastomers Natural Rubber, Synthetic Rubber Isoprene, Butadiene, Styrene

Additional Information on Polymers and Glucose

Polymers are large molecules made up of repeating smaller units called monomers. Carbohydrates, such as starch, glycogen, and cellulose, are biological polymers formed from monosaccharide monomers like glucose.

Glucose (\(\text{C}_6\text{H}_{12}\text{O}_6\)) is a fundamental energy source for most living organisms and is a key monomer in the synthesis of many important polysaccharides.

Natural rubber, on the other hand, is a polymer of isoprene (2-methyl-1,3-butadiene). The polymerization of isoprene forms long chains of polyisoprene, giving rubber its elastic properties. Its structure is fundamentally different from carbohydrate polymers.

Understanding the basic building blocks of different types of polymers helps in classifying them and understanding their properties and functions.

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