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Question

Which one of the following gives the highest amount of hydrogen ions(H +)?

This question was previously asked in
NDA I 2018 GAT Previous Year Paper (22-Apr-2018)
The correct answer is

Gastric juice

Understanding the acidity or alkalinity of a solution helps determine the concentration of hydrogen ions (H⁺). Substances that release more H⁺ ions into a solution are considered acidic, while those that release hydroxide ions (OH⁻) or accept H⁺ ions are considered basic or alkaline. The pH scale is used to measure the concentration of H⁺ ions; a lower pH indicates a higher concentration of H⁺ ions and thus higher acidity.

Analysing Hydrogen Ion Concentration in Different Solutions

Let's examine each option to understand its nature and relative concentration of hydrogen ions.

  1. Sodium hydroxide solution: Sodium hydroxide ($\text{NaOH}$) is a strong base. When dissolved in water, it dissociates almost completely into sodium ions ($\text{Na}^{+}$) and hydroxide ions ($\text{OH}^{-}$). Bases reduce the concentration of H⁺ ions in the solution by reacting with them to form water ($\text{H}_{2}\text{O}$) or by the high concentration of $\text{OH}^{-}$ ions shifting the equilibrium of water autoionization. Therefore, a sodium hydroxide solution has a very low concentration of H⁺ ions and a high pH (typically > 7).
  2. Milk of magnesia: Milk of magnesia is a suspension of magnesium hydroxide ($\text{Mg(OH)}_{2}$). This is a weak base, often used as an antacid to neutralize stomach acid. Being a base, it contains a relatively low concentration of H⁺ ions compared to acidic solutions. Its pH is typically around 10.
  3. Lemon juice: Lemon juice contains citric acid ($\text{C}_{6}\text{H}_{8}\text{O}_{7}$), which is a weak acid. Acids donate H⁺ ions when dissolved in water. Lemon juice is acidic, with a typical pH range of 2 to 3. This means it has a higher concentration of H⁺ ions than basic solutions like sodium hydroxide or milk of magnesia.
  4. Gastric juice: Gastric juice is found in the stomach and contains hydrochloric acid ($\text{HCl}$), which is a strong acid. Strong acids dissociate almost completely in water, releasing a high concentration of H⁺ ions. Gastric juice is highly acidic, with a typical pH range of 1.5 to 3.5. Due to the presence of the strong acid $\text{HCl}$, gastric juice generally has a lower pH and thus a significantly higher concentration of H⁺ ions compared to weak acidic solutions like lemon juice, and vastly higher than basic solutions.

Comparing Acidity and Hydrogen Ion Levels

To provide a clearer comparison, let's look at the typical pH ranges and infer the relative $\text{H}^{+}$ concentration:

Substance Nature Typical pH Range Relative $\text{H}^{+}$ Concentration
Sodium hydroxide solution Strong Base > 7 (e.g., 13-14 for concentrated) Very Low
Milk of magnesia Weak Base ~10 Low
Lemon juice Weak Acid 2 - 3 High
Gastric juice Strong Acid 1.5 - 3.5 Very High

Recall that a lower pH value corresponds to a higher concentration of hydrogen ions. Comparing the typical pH ranges, gastric juice generally has the lowest pH, particularly at the lower end of its range (pH 1.5). Lemon juice is also acidic (pH 2-3), but gastric juice is typically more acidic due to the presence of a strong acid ($\text{HCl}$) compared to the weak acid (citric acid) in lemon juice. Sodium hydroxide solution and milk of magnesia are basic, meaning they have high pH values and thus low concentrations of hydrogen ions.

Therefore, among the given options, gastric juice, being the most acidic, contains the highest amount of hydrogen ions ($\text{H}^{+}$).

Revision Table: Acidity and pH Basics

Concept Description
Hydrogen Ion ($\text{H}^{+}$) A positively charged ion, essentially a proton. Its concentration determines acidity.
Acidity A measure of the concentration of $\text{H}^{+}$ ions in a solution. Higher $\text{H}^{+}$ concentration means higher acidity.
Alkalinity (Basicity) A measure related to the concentration of $\text{OH}^{-}$ ions. Bases have low $\text{H}^{+}$ concentration.
pH Scale A logarithmic scale used to specify the acidity or basicity of an aqueous solution. pH = $-\log_{10}[\text{H}^{+}]$. Lower pH means higher acidity (more $\text{H}^{+}$).
Strong Acid An acid that dissociates completely in water, releasing many $\text{H}^{+}$ ions (e.g., $\text{HCl}$).
Weak Acid An acid that only partially dissociates in water, releasing fewer $\text{H}^{+}$ ions (e.g., citric acid).

Additional Information: Role of Acids and Bases

Acids and bases play crucial roles in many biological and chemical processes. In the human body, for instance, gastric juice's high acidity is essential for digesting food and killing harmful microorganisms. The pH of blood is tightly regulated within a narrow, slightly alkaline range (7.35-7.45). Many biological enzymes function optimally within specific pH ranges. Outside the body, acids and bases are used in various industrial processes, cleaning products, and food preparation.

Understanding the concept of $\text{H}^{+}$ concentration and its relation to pH is fundamental in chemistry and biology. The strength of an acid or base (whether it's strong or weak) directly impacts how many $\text{H}^{+}$ (or $\text{OH}^{-}$) ions are released into solution at a given concentration, thus affecting the overall acidity or basicity and the pH.

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