Which of the following substance has a pH value of about 14?
Sodium hydroxide
The pH scale is a measure used to specify the acidity or basicity of an aqueous solution. It ranges typically from 0 to 14. Solutions with a pH less than 7 are considered acidic, a pH of 7 is neutral (like pure water), and solutions with a pH greater than 7 are considered basic or alkaline. The pH value is inversely related to the concentration of hydrogen ions ($H^+$) in the solution.
A pH value of about 14 indicates a very strong basic or alkaline solution, meaning it has a very low concentration of $H^+$ ions and a very high concentration of hydroxide ions ($OH^-$).
Let's examine the typical pH range for each substance provided in the options:
We can summarize the approximate pH ranges of the substances:
| Substance | Typical pH Range | Nature |
|---|---|---|
| Blood | 7.35 - 7.45 | Slightly Alkaline |
| Sodium hydroxide | Up to 14 (for concentrated solutions) | Strongly Alkaline (Strong Base) |
| Milk of magnesia | 10 - 11 | Alkaline (Weak Base) |
| Lemon Juice | 2 - 3 | Acidic |
Based on the typical pH values, sodium hydroxide is the substance among the options that can have a pH value of about 14, especially when in a concentrated solution. Blood is slightly alkaline, milk of magnesia is a weaker base with a lower alkaline pH, and lemon juice is acidic.
| pH Range | Nature | Examples |
|---|---|---|
| 0 - < 7 | Acidic | Lemon juice, Vinegar, Stomach acid |
| = 7 | Neutral | Pure water |
| > 7 - 14 | Basic (Alkaline) | Blood, Milk of magnesia, Soapy water, Sodium hydroxide |
Strong bases like sodium hydroxide ($NaOH$) completely dissociate in water, releasing a high concentration of hydroxide ions ($OH^-$). This high concentration of $OH^-$ ions leads to a very low concentration of $H^+$ ions, resulting in a high pH value, potentially reaching 14 for a 1 molar solution.
Other examples of strong bases include potassium hydroxide ($KOH$) and barium hydroxide ($Ba(OH)_2$).
Weak bases, like magnesium hydroxide ($Mg(OH)_2$) in milk of magnesia, do not completely dissociate in water, resulting in a lower concentration of $OH^-$ ions compared to strong bases of similar concentration, and thus a lower pH.
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