Standard electrode potential of three metals A, B and C are respectively 0.5 V, −3 V and −1.2 V. Reducing power of these metals would be
B > C > A
Reducing power runs B > C > A — option 2.
The principle. A reducing agent is a substance that gives up electrons and is itself oxidised. The standard electrode potential quoted for a metal is its reduction potential; the more negative it is, the less willing the ion is to accept electrons, and therefore the more readily the metal loses them. So :
the more negative the standard reduction potential, the stronger the reducing agent.
| Metal | E° (V) | Position |
|---|---|---|
| A | +0·5 | Most positive — weakest reducing agent |
| C | −1·2 | Intermediate |
| B | −3·0 | Most negative — strongest reducing agent |
Arranging in decreasing order of reducing power gives B > C > A.
A check against a familiar case. Lithium has the most negative standard reduction potential of all, about −3·04 V, and is indeed among the strongest reducing agents known; fluorine has the most positive, about +2·87 V, and is the strongest oxidising agent. Metal B, at −3 V, is therefore behaving like an alkali metal, and metal A, at +0·5 V, like a noble metal such as copper or silver.
The link with the reactivity series. The electrochemical series is simply the reactivity series arranged by electrode potential. A metal higher in it — more negative — will displace one lower down from its salt solution, will react more vigorously with acids, and corrodes more readily. So metal B would displace both C and A from their solutions, and C would displace A.
The common error is to read the ranking straight from the numbers as printed, taking the largest value as the strongest. That gives A > C > B — option 1, placed there for precisely that mistake. Remember that oxidising power follows the positive direction and reducing power the negative.
Hence, the answer is B > C > A.
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