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Question

Metanil yellow, a non-permitted dye, is often used to adulterate turmeric. Which chemical test can confirm its presence?

This question was previously asked in
SSC Stenographer 2025 Question Paper (06-Aug-2025) Shift 2
The correct answer is
Alcohol and hydrochloric acid test yielding pink color

Detecting Metanil Yellow Adulteration in Turmeric

Turmeric is a common spice, but sometimes it can be adulterated with harmful synthetic dyes like Metanil yellow to make it appear more vibrant. Metanil yellow is not permitted for use in food products, making its detection crucial for food safety.

Understanding the Chemical Test for Metanil Yellow

A specific chemical test can reliably confirm the presence of Metanil yellow in turmeric. This test involves using alcohol and hydrochloric acid.

Procedure:

  • Take a small sample of the turmeric powder.
  • Add some alcohol (like ethanol) to the sample and mix it well.
  • Carefully add a few drops of hydrochloric acid (HCl) to the mixture.

Observation and Explanation:

If Metanil yellow is present as an adulterant, the mixture will turn a distinct pink color upon the addition of hydrochloric acid. This color change is characteristic of Metanil yellow when exposed to acidic conditions.

Metanil yellow is an acid dye. Its chemical structure allows it to change color in the presence of strong acids. The reaction essentially protonates the chromophore (color-bearing part) of the dye molecule, shifting its absorption spectrum and resulting in the observed pink hue.

Turmeric, being a natural spice, does not contain compounds that produce this specific pink color change when treated with alcohol and hydrochloric acid.

Evaluating Other Test Options

  • Adding vinegar and looking for bubbles: While vinegar (acetic acid) is an acid, this test is not specific for Metanil yellow and might not produce a clear or indicative result for this particular dye. It's more commonly associated with tests for carbonates.
  • Boiling in water and observing sediment: Boiling turmeric in water primarily checks for water-soluble components. While some dyes might dissolve, this method doesn't specifically identify Metanil yellow and isn't a confirmatory test.
  • Mixing with saltwater and checking for layers: This method relates to density or solubility differences, which are not specific indicators for the presence of Metanil yellow dye in turmeric.

Therefore, the alcohol and hydrochloric acid test yielding a pink color is the most reliable chemical method among the options provided to confirm the adulteration of turmeric with Metanil yellow.

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