List - I
(Number of d-electrons)List - II
(CFSE)A. $\text{d}^{6}$ I. $-0.4$ B. $\text{d}^{4}$ II. $-1.2$ C. $\text{d}^{7}$ III. $-0.8$ D. $\text{d}^{8}$ IV. $-0.6$
Choose the correct answer from the options given below :
Tetrahedral Complex CFSE Matching
This question requires matching the number of d-electrons in transition metal ions with their corresponding Crystal Field Stabilization Energy (CFSE) values specifically within tetrahedral complexes. We consider the standard splitting of d-orbitals in a tetrahedral ligand field.
CFSE Principles in Tetrahedral Geometry
In tetrahedral complexes, the d-orbitals split into a lower energy e set (2 orbitals) and a higher energy t2 set (3 orbitals). The energy difference is denoted as $ \Delta_t $. The CFSE calculation is based on the number of electrons occupying these sets, using coefficients relative to the barycenter:
$ \text{CFSE} = n_e \times (-0.4 \Delta_t) + n_{t_2} \times (+0.6 \Delta_t) $
The values in List-II are specific CFSE values provided for matching.
Matching d-Electrons to CFSE Values
The correct option (C) provides the following pairings:
| List - I (Number of d-electrons) | List - II (CFSE Value) |
| A. $ \text{d}^{6} $ | IV. $-0.6$ |
| B. $ \text{d}^{4} $ | I. $-1.2$ |
| C. $ \text{d}^{7} $ | II. $-0.8$ |
| D. $ \text{d}^{8} $ | III. $-0.4$ |
This comprehensive matching, as indicated by the correct answer, connects each d-electron configuration from List-I to its specified CFSE value from List-II.
Similar Questions
- Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : Boiling point of cis isomers is higher than trans isomers.
Reason (R) : The Dipole moment of cis isomers is higher than trans isomers.
In the light of the above statements, choose the most appropriate answer from the options given below : - Choose the correct sequence on the basis of number of unpaired electrons present in the given field :
A. $\text{Cr (+ II)}$ in weak field
B. $\text{Co (+ II)}$ in strong field
C. $\text{Ni (+ II)}$ in strong field
D. $\text{Pt (+ II)}$ in weak field
E. $\text{Ag (+ II)}$ in strong field
Choose the correct answer from the options given below : - Choose the correct sequence of the elements arranged in their increasing order of atomic numbers:
A. Pu
B. Po
C. Pm
D. Pt
E. Pa
Choose the correct answer from the options given below : Arrange the Hydrogen of the following compounds from most acidic to least acidic :
Choose the correct answer from the options given below :- Which of the following molecules possess V-shape ?
A. $\text{O}_{3}$
B. $\text{N}_{3}^{-}$
C. $\text{CO}_{3}^{2-}$
D. $\text{NO}_{2}^{-}$
E. $\text{NO}_{3}^{-}$
Choose the most appropriate answer from the options given below : - Which of the silanes are formed by the reactions of $\text{Mg}_{2}\text{Si}+\text{H}_{2}\text{SO}_{4} \longrightarrow$
A. $\text{Si}_{4}\text{H}_{10}$
B. $\text{Si}_{3}\text{H}_{8}$
C. $\text{Si}_{5}\text{H}_{10}$
D. $\text{Si}_{6}\text{H}_{14}$
E. $\text{Si}_{7}\text{H}_{9}$
Choose the correct answer from the options given below : - The known per-oxoacids of Sulphur are :
A. $\text{H}_{2}\text{SO}_{5}$
B. $\text{H}_{2}\text{S}_{2}\text{O}_{9}$
C. $\text{H}_{3}\text{S}_{4}\text{O}_{12}$
D. $\text{H}_{2}\text{S}_{2}\text{O}_{8}$
E. $\text{H}_{2}\text{S}_{2}\text{O}_{7}$
Choose the correct answer from the options given below : - Which of the following conditions should be met while writing the canonical structures of a resonance hybrid ?
A. The magnitude of resonance energy should be low and the hybrid will be more stable
B. The number of unpaired electrons should be same in all the canonical forms
C. Canonical forms where similar charges develop on vicinal atoms are highly significant forms
D. The positions of the nuclei of each canonical form and the hybrid must remain same
E. Only a pair of electrons should be shifted in writing the canonical forms
Choose the correct answer from the options given below : - Match List - I with List - II.
List - I List - II A. Root mean square speed I. $(8 \text{ kT}/\pi\mu)^{1/2}$ B. Mean speed II. $(8 \text{ RT}/\pi\text{M})^{1/2}$ C. Most probable speed III. $(3 \text{ RT}/\text{M})^{1/2}$ D. Mean relative speed IV. $(2 \text{ RT}/\text{M})^{1/2}$
Choose the correct answer from the options given below : - During ion-implantation, the impurity atoms entering the crystal, gives up their energy to the lattice via collisions. These impurity atoms come to rest at certain average penetration depth known as :
Important Questions from Miscellaneous
- Which of the following relationships is/are not true?
(A). Most probable velocity = $\sqrt{\frac{2RT}{M}}$
(B). PV = $\frac{3}{2}kT$
(C). Compressibility factor Z = $\frac{pV}{nRT}$
(D). Average kinetic energy of gas = $\frac{1}{2}kT$
Choose the correct answer from the options given below - Match List-I with List-II
List-I List-II Electronic Configuration First Ionisation energy (kJ mol$^{-1}$) (A). ns$^2$ (I). 2100 (B). ns$^2$np$^1$ (II). 1400 (C). ns$^2$np$^3$ (III). 800 (D). ns$^2$np$^6$ (IV). 900
Choose the correct answer from the options given below: - The shielding constant of a 2p electron (calculated using Slater's rules) is
- Match List-I with List-II
List-I List-II Spectroscopy Property (A). Raman (I). Polarizability (B). FTIR (II). Dipole Moment (C). UV-Visible (III). Absorbance (D). NMR (IV). Spin
Choose the correct answer from the options given below: - The structure of protein comprises of:
(A). Primary structure of protein is associated with amino acids
(B). Secondary structure of protein is associated to peptides
(C). Tertiary structure of protein is associated with polypeptide chains
(D). Quaternary structure of protein is associated with polypeptide chains
Choose the correct answer from the options given below:
