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Question

Match List I with List II :

List I (Quantum Numbers )

$n$, $l$

List II (Orbital)
A. 2, 1I. 3d
B. 4, 0II. 2p
C. 5, 3III. 4s
D. 3, 2IV. 5f

Choose the correct answer from the options given below :

This question was previously asked in
NEET UG Re-Exam 2026 Question Paper (21-Jun-2026)
The correct answer is
A-II, B-III, C-IV, D-I

Matching Quantum Numbers ($n, l$) to Atomic Orbitals

To match the quantum numbers ($n$, $l$) with the correct atomic orbital notation, we need to understand the meaning of each quantum number:

  • The principal quantum number, $n$, indicates the electron shell or energy level. It can be any positive integer ($1, 2, 3, \dots$).
  • The azimuthal or angular momentum quantum number, $l$, indicates the shape of the orbital and the subshell. The possible values of $l$ range from $0$ to $n-1$.
    • $l=0$ corresponds to an 's' orbital.
    • $l=1$ corresponds to a 'p' orbital.
    • $l=2$ corresponds to a 'd' orbital.
    • $l=3$ corresponds to an 'f' orbital.

The orbital notation is formed by combining the value of $n$ with the letter corresponding to $l$ (e.g., $n=2, l=1$ is denoted as 2p).

Matching Process

Let's match each pair from List I to List II:

  • A. $n=2, l=1$: Since $l=1$, it represents a 'p' orbital. With $n=2$, the orbital is 2p. This matches with II.
  • B. $n=4, l=0$: Since $l=0$, it represents an 's' orbital. With $n=4$, the orbital is 4s. This matches with III.
  • C. $n=5, l=3$: Since $l=3$, it represents an 'f' orbital. With $n=5$, the orbital is 5f. This matches with IV.
  • D. $n=3, l=2$: Since $l=2$, it represents a 'd' orbital. With $n=3$, the orbital is 3d. This matches with I.

Summary of Matches

List I Item Quantum Numbers ($n, l$) List II Item Corresponding Orbital
A (2, 1) II 2p
B (4, 0) III 4s
C (5, 3) IV 5f
D (3, 2) I 3d

The correct matching is A-II, B-III, C-IV, D-I.

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