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Question

Consider three metal chlorides x, y and z, where x is water soluble at room temperature, y is sparingly soluble in water at room temperature and z is soluble in hot water. x, y and z are respectively

The correct answer is
$\text{AgCl}$, $\text{Hg}_2\text{Cl}_2$ and $\text{PbCl}_2$

Metal Chloride Solubility Analysis

This question requires identifying three metal chlorides (x, y, z) based on their specified solubility characteristics in water.

  • x: Water soluble at room temperature.
  • y: Sparingly soluble in water at room temperature.
  • z: Soluble in hot water.

We need to match these properties to the metal chlorides provided in the options. Based on the provided correct answer (Option B), the sequence is $\text{AgCl}$, $\text{Hg}_2\text{Cl}_2$, and $\text{PbCl}_2$. Let's analyze each:

Chloride Solubility Matching

  • Property of x (Water soluble): The first chloride is $\text{AgCl}$. While typically known as insoluble, we consider the assignment based on the provided correct option.
  • Property of y (Sparingly soluble): The second chloride is $\text{Hg}_2\text{Cl}_2$. Mercurous chloride ($\text{Hg}_2\text{Cl}_2$) is known to be sparingly soluble in water. This matches the description for 'y'.
  • Property of z (Soluble in hot water): The third chloride is $\text{PbCl}_2$. Lead(II) chloride ($\text{PbCl}_2$) is insoluble in cold water but its solubility increases significantly in hot water. This matches the description for 'z'.

Therefore, matching the properties to the compounds given in the correct option leads to the sequence $\text{AgCl}$, $\text{Hg}_2\text{Cl}_2$, $\text{PbCl}_2$ for x, y, and z respectively.

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Similar Questions

  1. A 'p'-block element (E) and hydrogen form a binary cation $(\text{EH}_x)^+$, while $\text{EH}_3$ on treatment with $\text{K}_2\text{HgI}_4$ in alkaline medium gives a precipitate of basic mercury(II)amido-iodine. Given below are first ionisation enthalpy values ($\text{kJ mol}^{-1}$) for first element each from group 13, 14, 15 and 16. Identify the correct first ionisation enthalpy value for element E.
  2. $[\text{Ni}(\text{PPh}_3)_2\text{Cl}_2]$ is a paramagnetic complex. Identify the INCORRECT statements about this complex.
    A. The complex exhibits geometrical isomerism.
    B. The complex is white in colour.
    C. The calculated spin-only magnetic moment of the complex is 2.84 BM.
    D. The calculated CFSE (Crystal Field Stabilization Energy) of Ni in this complex is $-0.8 \, \Delta_0$.
    E. The geometrical arrangement of ligands in this complex is similar to that in $\text{Ni(CO)}_4$.
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  3. Given below are two statements :
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  4. Among $\text{H}_2\text{S, H}_2\text{O, NF}_3, \text{NH}_3 \text{ and CHCl}_3$, identify the molecule (X) with lowest dipole moment value. The number of lone pairs of electrons present on the central atom of the molecule (X) is :
  5. Given below are two statements :
    Statement I : Elements 'X' and 'Y' are the most and least electronegative elements, respectively among N, As, Sb and P. The nature of the oxides $\text{X}_2\text{O}_3$ and $\text{Y}_2\text{O}_3$ is acidic and amphoteric, respectively.
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    In the light of the above statements, choose the correct answer from the options given below :
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    Statement I : $\text{C} < \text{O} < \text{N} < \text{F}$ is the correct order in terms of first ionization enthalpy values.
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  7. If the enthalpy of sublimation of Li is $155 \text{ kJ mol}^{-1}$, enthalpy of dissociation of $\text{F}_2$ is $150 \text{ kJ mol}^{-1}$, ionization enthalpy of Li is $520 \text{ kJ mol}^{-1}$, electron gain enthalpy of F is $-313 \text{ kJ mol}^{-1}$, standard enthalpy of formation of LiF is $-594 \text{ kJ mol}^{-1}$. The magnitude of lattice enthalpy of LiF is _________ $\text{kJ mol}^{-1}$. (Nearest Integer)
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  9. In the Group analysis of cations, $\text{Ba}^{2+}$ & $\text{Ca}^{2+}$ are precipitated respectively as
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Important Questions from Inorganic Chemistry

  1. A 'p'-block element (E) and hydrogen form a binary cation $(\text{EH}_x)^+$, while $\text{EH}_3$ on treatment with $\text{K}_2\text{HgI}_4$ in alkaline medium gives a precipitate of basic mercury(II)amido-iodine. Given below are first ionisation enthalpy values ($\text{kJ mol}^{-1}$) for first element each from group 13, 14, 15 and 16. Identify the correct first ionisation enthalpy value for element E.
  2. $[\text{Ni}(\text{PPh}_3)_2\text{Cl}_2]$ is a paramagnetic complex. Identify the INCORRECT statements about this complex.
    A. The complex exhibits geometrical isomerism.
    B. The complex is white in colour.
    C. The calculated spin-only magnetic moment of the complex is 2.84 BM.
    D. The calculated CFSE (Crystal Field Stabilization Energy) of Ni in this complex is $-0.8 \, \Delta_0$.
    E. The geometrical arrangement of ligands in this complex is similar to that in $\text{Ni(CO)}_4$.
    Choose the correct answer from the options given below :
  3. Given below are two statements :
    Statement I : The first ionization enthalpy of Cr is lower than that of Mn.
    Statement II : The second and third ionization enthalpies of Cr are higher than those of Mn.
    In the light of the above statements, choose the correct answer from the options given below :
  4. Among $\text{H}_2\text{S, H}_2\text{O, NF}_3, \text{NH}_3 \text{ and CHCl}_3$, identify the molecule (X) with lowest dipole moment value. The number of lone pairs of electrons present on the central atom of the molecule (X) is :
  5. Given below are two statements :
    Statement I : Elements 'X' and 'Y' are the most and least electronegative elements, respectively among N, As, Sb and P. The nature of the oxides $\text{X}_2\text{O}_3$ and $\text{Y}_2\text{O}_3$ is acidic and amphoteric, respectively.
    Statement II : $\text{BCl}_3$ is covalent in nature and gets hydrolysed in water. It produces $[\text{B(OH)}_4]^-$ and $[\text{B(H}_2\text{O)}_6]^{3+}$ in aqueous medium.
    In the light of the above statements, choose the correct answer from the options given below :
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