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Question

An ideal gas exists in a state with pressure $P_0$, volume $V_0$. It is isothermally expanded to $4$ times of its initial volume($V_0$), then isobarically compressed to its original volume. Finally the system is heated isochorically to bring it to its initial state. The amount of heat exchanged in this process is

The correct answer is
$P_0V_0 (2\ln 2 – 0.75)$

This problem requires calculating the total heat exchanged during a thermodynamic cycle for an ideal gas. According to the First Law of Thermodynamics, for a cyclic process where the system returns to its initial state, the total change in internal energy ($\Delta U$) is zero. Consequently, the total heat exchanged ($Q_{total}$) equals the total work done ($W_{total}$).

Ideal Gas Process Stages

The process involves three distinct stages:

  1. Stage 1: Isothermal Expansion: The gas expands from an initial state ($P_0, V_0$) to a final state ($P_1, V_1 = 4V_0$) at a constant temperature ($T_0$).
  2. Stage 2: Isobaric Compression: The gas is compressed from state ($P_1, V_1 = 4V_0$) to a final state ($P_2, V_2 = V_0$) at constant pressure ($P_1$).
  3. Stage 3: Isochoric Heating: The gas is heated from state ($P_2, V_2 = V_0$) back to its initial state ($P_0, V_0$) at constant volume ($V_2$).

Work Done Calculation Per Stage

We calculate the work done ($W$) for each stage:

Isothermal Expansion Work

  • For an isothermal process, the work done is given by $W = nRT \ln(V_f/V_i)$. Using the ideal gas law $P_0V_0 = nRT_0$, the work done in Stage 1 is:
  • $W_1 = P_0V_0 \ln\left(\frac{4V_0}{V_0}\right) = P_0V_0 \ln 4 = P_0V_0 \ln(2^2) = 2P_0V_0 \ln 2$

Isobaric Compression Work

  • First, determine the pressure during the isobaric process. From $P_1V_1 = P_0V_0$, we get $P_1(4V_0) = P_0V_0$, so $P_1 = P_0/4$. This pressure is constant for Stage 2.
  • For an isobaric process, work done is $W = P \Delta V$.
  • $W_2 = P_1(V_2 - V_1) = \left(\frac{P_0}{4}\right)(V_0 - 4V_0) = \left(\frac{P_0}{4}\right)(-3V_0) = -\frac{3}{4} P_0V_0$

Isochoric Heating Work

  • In an isochoric process, the volume remains constant.
  • $W_3 = 0$

Total Heat Exchanged Calculation

The total work done ($W_{total}$) over the entire cycle is the sum of the work done in each stage:

$W_{total} = W_1 + W_2 + W_3$

$W_{total} = 2P_0V_0 \ln 2 + \left(-\frac{3}{4} P_0V_0\right) + 0$

$W_{total} = P_0V_0 \left(2 \ln 2 - \frac{3}{4}\right)$

Since the process is a cycle, $\Delta U_{total} = 0$. Therefore, the total heat exchanged is:

$Q_{total} = W_{total} = P_0V_0 \left(2 \ln 2 - \frac{3}{4}\right)$

Expressing the fraction as a decimal ($3/4 = 0.75$), we get:

$Q_{total} = P_0V_0 (2 \ln 2 - 0.75)$

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Similar Questions

  1. During the melting of a slab of ice at $273 \ K$ at atmospheric pressure:

  2. $\gamma_A$ is the specific heat ratio of monoatomic gas A having 3 translational degrees of freedom. $\gamma_B$ is the specific heat ratio of polyatomic gas B having 3 translational, 3 rotational degrees of freedom and 1 vibrational mode. If $\frac{\gamma_A}{\gamma_B} = \left(1 + \frac{1}{n}\right)$, then the value of n is _________.
  3. Match List - I with List - II.
    List - IList - II
    (A) Isobaric(I) $\Delta Q = \Delta W$
    (B) Isochoric(II) $\Delta Q = \Delta U$
    (C) Adiabatic(III) $\Delta Q = \text{zero}$
    (D) Isothermal(IV) $\Delta Q = \Delta U + P\Delta V$
    $\Delta Q$=Heat supplied
    $\Delta W$ = Work done by the system
    $\Delta U$=Change in internal energy
    P = Pressure of the system
    $\Delta V$ = Change in volume of the system
    Choose the correct answer from the options given below :
  4. There are two vessels filled with an ideal gas where volume of one is double the volume of other. The large vessel contains the gas at 8 kPa at 1000 K while the smaller vessel contains the gas at 7 kPa at 500 K. If the vessels are connected to each other by a thin tube allowing the gas to flow and the temperature of both vessels is maintained at 600 K, at steady state the pressure in the vessels will be (in kPa).
  5. Match the LIST-I with LIST-II Choose the correct answer from the options given below:

     

  6. An ideal gas has undergone through the cyclic process as shown in the figure. Work done by the gas in the entire cycle is ________ $\times 10^{-1}$J.

    (Take $\pi = 3.14$)

  7. Water falls from a height of $200 \text{ m}$ into a pool. Calculate the rise in temperature of the water assuming no heat dissipation from the water in the pool.

     (Take $g = 10 \text{ m/s}^2$, specific heat of water $= 4200 \text{ J/(kg K)}$)

  8. A monoatomic gas having $\gamma = \frac{5}{3}$ is stored in a thermally insulated container and the gas is suddenly compressed to $\frac{1}{8}^{\text{th}}$ of its initial volume. The ratio of final pressure and initial pressure is: 

    ($\gamma$ is the ratio of specific heats of the gas at constant pressure and at constant volume)

  9. A body takes 10 minutes to cool from $60^\circ C$ to $50^\circ C$. The temperature of surroundings is constant at $25^\circ C$. Then, the temperature of the body after next 10 minutes will be approximately :
  10. The value closest to the thermal velocity of a Helium atom at room temperature (300 K) in $ms^{-1}$ is : [$k_B = 1.4 \times 10^{-23}$ J/K; $m_{He} = 7 \times 10^{-27}$ kg]

Important Questions from Heat and Thermodynamics

  1. During the melting of a slab of ice at $273 \ K$ at atmospheric pressure:

  2. $\gamma_A$ is the specific heat ratio of monoatomic gas A having 3 translational degrees of freedom. $\gamma_B$ is the specific heat ratio of polyatomic gas B having 3 translational, 3 rotational degrees of freedom and 1 vibrational mode. If $\frac{\gamma_A}{\gamma_B} = \left(1 + \frac{1}{n}\right)$, then the value of n is _________.
  3. Match List - I with List - II.
    List - IList - II
    (A) Isobaric(I) $\Delta Q = \Delta W$
    (B) Isochoric(II) $\Delta Q = \Delta U$
    (C) Adiabatic(III) $\Delta Q = \text{zero}$
    (D) Isothermal(IV) $\Delta Q = \Delta U + P\Delta V$
    $\Delta Q$=Heat supplied
    $\Delta W$ = Work done by the system
    $\Delta U$=Change in internal energy
    P = Pressure of the system
    $\Delta V$ = Change in volume of the system
    Choose the correct answer from the options given below :
  4. There are two vessels filled with an ideal gas where volume of one is double the volume of other. The large vessel contains the gas at 8 kPa at 1000 K while the smaller vessel contains the gas at 7 kPa at 500 K. If the vessels are connected to each other by a thin tube allowing the gas to flow and the temperature of both vessels is maintained at 600 K, at steady state the pressure in the vessels will be (in kPa).
  5. Match the LIST-I with LIST-II Choose the correct answer from the options given below:

     

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