Silver (Ag) typically turns black due to a chemical reaction with substances containing sulfur in the environment. The most common cause is hydrogen sulfide ($H_2S$), a gas present in the air.
The reaction forms silver sulfide ($Ag_2S$), a black compound, on the surface of the silver.
The simplified reaction is:
$2Ag + H_2S \rightarrow Ag_2S (black) + H_2$
Therefore, sulfur is the substance responsible for silver turning black.
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