Which one of the following is used in soda-acid fire extinguishers?
Sodium hydrogen carbonate
Understanding Soda-Acid Fire Extinguishers
Soda-acid fire extinguishers are a classic type of fire safety equipment, primarily designed to tackle Class A fires, which involve ordinary combustible materials like wood, paper, and textiles. The key to their operation lies in a chemical reaction that produces a large volume of carbon dioxide gas.
The main components held within a soda-acid fire extinguisher are:
- A solution containing sodium hydrogen carbonate (also known as sodium bicarbonate or baking soda).
- A small bottle or container holding an acid, typically concentrated sulfuric acid ($\text{H}_2\text{SO}_4$).
When the extinguisher is activated (usually by inverting it or breaking a seal), the acid mixes with the sodium hydrogen carbonate solution. This mixing triggers a chemical reaction that generates carbon dioxide gas.
The chemical reaction is:
\(\text{2NaHCO}_3\text{(aq)} + \text{H}_2\text{SO}_4\text{(aq)} \rightarrow \text{Na}_2\text{SO}_4\text{(aq)} + \text{2H}_2\text{O(l)} + \text{2CO}_2\text{(g)}\)
This reaction produces sodium sulfate, water, and crucially, carbon dioxide gas. The rapid generation of carbon dioxide gas builds pressure inside the extinguisher, expelling the contents (a mixture of water and carbon dioxide) onto the fire.
Carbon dioxide works as a fire extinguishing agent by:
- Displacing oxygen around the fire, effectively smothering it.
- Cooling the burning material slightly, although its primary effect is oxygen displacement.
Therefore, the essential ingredient from the options provided, which is used in soda-acid fire extinguishers, is sodium hydrogen carbonate.
Analyzing the Options
Let's look at why the other options are not used as the primary soda component in this type of extinguisher:
- Sodium chloride ($\text{NaCl}$): This is common table salt. While it can have some fire suppressant properties in certain applications (like metal fires), it does not react with common acids to produce a significant amount of carbon dioxide gas needed for a soda-acid extinguisher.
- Calcium hydroxide ($\text{Ca(OH)}_2$): Also known as slaked lime, calcium hydroxide is a base. While it can react with acids, the reaction with sulfuric acid would produce calcium sulfate and water. It does not efficiently produce the large volume of carbon dioxide gas required for this type of extinguisher from a reaction with typical acids used.
- Acetic acid ($\text{CH}_3\text{COOH}$): Acetic acid is an acid, not the 'soda' component. In a soda-acid extinguisher, you have a 'soda' (a bicarbonate) and an acid. Acetic acid *could* potentially be used as the acid component to react with sodium hydrogen carbonate, but the question asks for the 'soda' part, and acetic acid itself is an acid. More commonly, sulfuric acid is used because it is a strong acid and reacts vigorously to produce $\text{CO}_2$.
Based on the composition and working principle of soda-acid fire extinguishers, sodium hydrogen carbonate is the correct answer as the 'soda' component.
| Component | Chemical Name | Role |
|---|---|---|
| Soda (Powder/Solution) | Sodium hydrogen carbonate ($\text{NaHCO}_3$) | Reacts with acid to produce $\text{CO}_2$ |
| Acid | Sulfuric acid ($\text{H}_2\text{SO}_4$) (Typically) | Reacts with sodium hydrogen carbonate |
Revision Table: Key Facts
| Feature | Description |
|---|---|
| Primary Use | Class A fires (combustibles like wood, paper) |
| Key Chemical Components | Sodium hydrogen carbonate ($\text{NaHCO}_3$) and an acid (e.g., $\text{H}_2\text{SO}_4$) |
| Extinguishing Agent | Carbon dioxide ($\text{CO}_2$) gas and water |
| How it Works | Chemical reaction produces $\text{CO}_2$, which smothers the fire. |
| Reaction Equation | \(\text{2NaHCO}_3 + \text{H}_2\text{SO}_4 \rightarrow \text{Na}_2\text{SO}_4 + \text{2H}_2\text{O} + \text{2CO}_2\) |
Additional Information on Fire Extinguisher Types
While soda-acid extinguishers were common historically, modern fire extinguishers use various agents suited for different fire classes. Understanding these types is important for fire safety:
- Water Extinguishers: Used for Class A fires. They cool the burning material.
- Foam Extinguishers: Used for Class A and Class B (flammable liquids) fires. They cool and create a barrier to smother the fire.
- Dry Powder Extinguishers: Used for Class A, B, and C (flammable gases) fires, and some for metal fires (Class D). They interrupt the chemical reaction of the fire and smother.
- CO$_2$ Extinguishers: Used for Class B and C fires. They displace oxygen. They are non-conductive, making them suitable for electrical fires (though powder is often preferred).
- Wet Chemical Extinguishers: Used for Class F (cooking oils/fats) fires. They cool and create a soapy layer to prevent re-ignition.
Knowing the correct type of extinguisher for a specific fire is crucial for effective and safe fire fighting.
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Match List-I with List-II and select the correct answer using the code given below the Lists :
List-I
(Trade Name)List-II
(Chemical Name)A. Bleaching powder 1. Sodium bicarbonate B. Baking soda 2. Sodium carbonate, 10 water C. Washing soda 3. Calcium oxychloride D. Plaster of Paris 4. Calcium sulphate, \(\frac{1}{2}\) water
Code:
A B C D
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