The question asks for the vaccine that was utilized first for human immunization and was subsequently included in the Expanded Program on Immunization (EPI).
The Expanded Program on Immunization (EPI), established by the World Health Organization (WHO) in 1974, aimed to ensure all children had access to essential vaccines. BCG was a foundational vaccine included from the program's inception due to its established role in preventing severe forms of tuberculosis.
Comparing the historical timelines and the core mandate of EPI, the BCG vaccine uniquely fulfills both criteria: being among the very first vaccines used for human immunization and being a key component of the EPI.
| List-I | List-II |
| Electronic Configuration | First Ionisation energy (kJ mol$^{-1}$) |
| (A). ns$^2$ | (I). 2100 |
| (B). ns$^2$np$^1$ | (II). 1400 |
| (C). ns$^2$np$^3$ | (III). 800 |
| (D). ns$^2$np$^6$ | (IV). 900 |
| List-I | List-II |
| Spectroscopy | Property |
| (A). Raman | (I). Polarizability |
| (B). FTIR | (II). Dipole Moment |
| (C). UV-Visible | (III). Absorbance |
| (D). NMR | (IV). Spin |