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Question

Which of the following is an unsaturated hydrocarbon?

This question was previously asked in
RRB ALP 2018 CBT 2 Fitter Question Paper (21-Jan-2019) (Shift 3)
The correct answer is

Ethyne

Understanding Hydrocarbons and Saturation

Hydrocarbons are organic compounds that are composed entirely of hydrogen and carbon atoms. They are the principal constituents of petroleum and natural gas.

Hydrocarbons are broadly classified based on the types of bonds between carbon atoms:

  • Saturated Hydrocarbons: These hydrocarbons contain only single bonds between carbon atoms. Alkanes are examples of saturated hydrocarbons. Their general formula is $\text{C}_n\text{H}_{2n+2}$.
  • Unsaturated Hydrocarbons: These hydrocarbons contain at least one double or triple bond between carbon atoms. Alkenes contain at least one carbon-carbon double bond, and alkynes contain at least one carbon-carbon triple bond. Alkenes have the general formula $\text{C}_n\text{H}_{2n}$, and alkynes have the general formula $\text{C}_n\text{H}_{2n-2}$.

Analyzing the Given Options for Unsaturated Hydrocarbons

Let's examine each option provided to determine which is an unsaturated hydrocarbon:

  1. Ethyne: Ethyne is an alkyne with the molecular formula $\text{C}_2\text{H}_2$. Its structure is $\text{H}-\text{C}\equiv\text{C}-\text{H}$. It contains a carbon-carbon triple bond. According to our definition, compounds with triple bonds are unsaturated hydrocarbons.

  2. Propane: Propane is an alkane with the molecular formula $\text{C}_3\text{H}_8$. Its structure contains only carbon-carbon single bonds ($\text{CH}_3-\text{CH}_2-\text{CH}_3$). Alkanes are saturated hydrocarbons.

  3. Butane: Butane is an alkane with the molecular formula $\text{C}_4\text{H}_{10}$. It contains only carbon-carbon single bonds. Alkanes are saturated hydrocarbons.

  4. Pentane: Pentane is an alkane with the molecular formula $\text{C}_5\text{H}_{12}$. It contains only carbon-carbon single bonds. Alkanes are saturated hydrocarbons.

Identifying the Unsaturated Hydrocarbon

Based on the analysis:

  • Ethyne contains a triple bond, making it unsaturated.
  • Propane, Butane, and Pentane are alkanes containing only single bonds, making them saturated.

Therefore, Ethyne is the unsaturated hydrocarbon among the given options.

Hydrocarbon Formula Bond Type(s) Classification
Ethyne $\text{C}_2\text{H}_2$ Triple bond ($\equiv$) Unsaturated (Alkyne)
Propane $\text{C}_3\text{H}_8$ Single bonds (-) Saturated (Alkane)
Butane $\text{C}_4\text{H}_{10}$ Single bonds (-) Saturated (Alkane)
Pentane $\text{C}_5\text{H}_{12}$ Single bonds (-) Saturated (Alkane)

Revision Table: Saturated vs Unsaturated Hydrocarbons

Feature Saturated Hydrocarbons Unsaturated Hydrocarbons
Carbon-Carbon Bonds Only single bonds Contain at least one double or triple bond
Examples Alkanes (e.g., Methane, Ethane, Propane) Alkenes (e.g., Ethene, Propene)
Alkynes (e.g., Ethyne, Propyne)
General Formula $\text{C}_n\text{H}_{2n+2}$ Alkenes: $\text{C}_n\text{H}_{2n}$
Alkynes: $\text{C}_n\text{H}_{2n-2}$

Additional Information on Hydrocarbon Types

Understanding the different types of hydrocarbons is crucial in organic chemistry. Let's delve a bit deeper:

  • Alkanes: These are the simplest class of hydrocarbons, consisting entirely of single bonds and hydrogen atoms. They are also known as paraffins. They are relatively unreactive compared to unsaturated hydrocarbons.
  • Alkenes: These hydrocarbons contain at least one carbon-carbon double bond. The presence of the double bond makes them more reactive than alkanes, undergoing addition reactions easily. The simplest alkene is Ethene ($\text{C}_2\text{H}_4$).
  • Alkynes: These hydrocarbons contain at least one carbon-carbon triple bond. Like alkenes, the triple bond makes them highly reactive, participating in addition reactions. The simplest alkyne is Ethyne ($\text{C}_2\text{H}_2$), also commonly known as acetylene.

The terms 'saturated' and 'unsaturated' relate to the number of hydrogen atoms attached to the carbon chain. Saturated hydrocarbons have the maximum possible number of hydrogen atoms for a given number of carbon atoms, while unsaturated hydrocarbons have fewer hydrogen atoms because of the presence of double or triple bonds.

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