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Question

Which of the following alkyl halides will undergo SN1 reaction most readily?

The correct answer is

(CH3)3C-I

The SN1 reaction involves the formation of a carbocation intermediate. The ability of the alkyl halide to undergo this reaction depends on the ability of the leaving group to stabilize the carbocation. In this case, **iodide (I-)** is the best leaving group, making **(CH3)3C-I** the most reactive in the SN1 reaction. The leaving group ability decreases in the order: I- > Br- > Cl- > F-. Therefore, the correct answer is **option (d)**.

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Important Questions from Haloalkanes and Haloarenes

  1. Which of the following haloalkanes reacts with aqueous KOH most easily?

  2. Which of the following is not a characteristic of enzymes?

  3. The relative reactivity order of the following halides towards Sn1 reaction is:

    (I)

    (II) CH3–CH2–Cl

    (III) CH3Cl

    (IV) Ph2CHCl

  4. What will be the product for the following reactions?

  5. From the following, choose the ones which are not secondary haloalkanes:

    (A) 2-Bromopentane

    (B) 1-Bromo-3-methylbutane

    (C) 3-Bromopentane

    (D) 2-Bromo-2-methylbutane

    (E) 2-Bromo-3-methylbutane

    Choose the correct answer from the options given below:

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