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Question

Water gas is a mixture of:

This question was previously asked in
NDA 2 2024 GAT Question Paper (01-Sep-2024)
The correct answer is

CO and H2

Understanding Water Gas Composition

The question asks about the composition of water gas. Water gas is an important industrial fuel gas mixture.

Let's look at the options provided:

  • Option 1: CO and H2
  • Option 2: CO2 and H2
  • Option 3: CO2 and H2O
  • Option 4: CO and H2O

Water gas is traditionally produced by passing steam over heated carbon (like coke or coal). The main chemical reaction involves the reaction between steam (\( \text{H}_2\text{O} \)) and carbon (\( \text{C} \)) at high temperatures (around 1000°C). This process is known as the water-gas shift reaction or steam reforming.

The primary reaction is:

\( \text{C(s)} + \text{H}_2\text{O(g)} \rightarrow \text{CO(g)} + \text{H}_2\text{(g)} \)

This reaction shows that the main products are carbon monoxide (\( \text{CO} \)) and hydrogen gas (\( \text{H}_2 \)). The mixture of these two gases is known as water gas or sometimes synthesis gas (syngas) when produced via this method, although syngas can have other compositions depending on the feedstock.

Therefore, the correct composition of water gas is carbon monoxide (\( \text{CO} \)) and hydrogen (\( \text{H}_2 \)).

Let's consider why the other options are incorrect:

  • CO2 and H2: While carbon dioxide (\( \text{CO}_2 \)) can be present in smaller amounts as a byproduct due to side reactions (like the water-gas shift reaction \( \text{CO} + \text{H}_2\text{O} \rightleftharpoons \text{CO}_2 + \text{H}_2 \)), it is not the primary defining component alongside hydrogen in typical water gas production.
  • CO2 and H2O: This mixture is not water gas. Water (\( \text{H}_2\text{O} \)) is a reactant in the production of water gas, not a primary component of the resulting gas mixture. Carbon dioxide is a possible byproduct.
  • CO and H2O: Again, water (\( \text{H}_2\text{O} \)) is a reactant (in steam form) used to produce water gas, not a main component of the product gas mixture alongside carbon monoxide.

Based on the definition and production method, water gas is fundamentally a mixture of carbon monoxide and hydrogen.

Revision Table: Components of Common Industrial Gases

Gas Name Primary Components Notes
Water Gas CO and H2 Produced from steam and carbon
Producer Gas CO, N2, small amounts of H2, CO2 Produced from air and carbon
Syngas (Synthesis Gas) Primarily CO and H2 Can have varying ratios and other components; feedstock dependent
Natural Gas Primarily Methane (CH4) Fossil fuel

Additional Information on Water Gas and Syngas

Water gas is a specific type of synthesis gas (syngas). Syngas is a fuel gas mixture consisting primarily of hydrogen, carbon monoxide, and often some carbon dioxide. Its name comes from its use in creating synthetic natural gas (SNG) or for producing ammonia or methanol.

The ratio of CO to H2 in water gas can be adjusted depending on the reaction conditions and purpose. Water gas itself is flammable and can be used as a fuel, but it is also a crucial intermediate in many chemical processes, particularly in the production of other chemicals and fuels.

The process of creating water gas from steam and carbon is endothermic, meaning it requires heat input. This is often done by alternating the flow of steam with a blast of air to heat the carbon source by burning some of it.

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