The set(s) of reagents that will effect the following conversion is(are)
The given conversion involves transforming a carbonyl group (ketone) into an aldehyde. We'll evaluate the sets of reagents to see which can accomplish this transformation.
i) \(\text{Ph}_3\text{P}=\text{CHOMe}\); ii) \(\text{H}_3\text{O}^+\)
This set of reagents implies a Wittig reaction followed by hydrolysis. The Wittig reaction with \(\text{Ph}_3\text{P}=\text{CHOMe}\) forms a new carbon-carbon double bond, which is then hydrolyzed by \(\text{H}_3\text{O}^+\) to yield an aldehyde. This sequence is suitable for converting the ketone group to an aldehyde.
i) \(\text{Me}_3\text{SI}, \text{NaH}\); ii) \(\text{BF}_3 \cdot \text{OEt}_2\)
This combination involves methylation followed by treatment with a Lewis acid. Here, methylation can lead to the formation of a methoxy group, and with the help of \(\text{BF}_3 \cdot \text{OEt}_2\), the intermediate can rearrange to produce an aldehyde. This sequence also achieves the desired conversion.
i) \(\text{TsNHNH}_2\); ii) \({^n}\text{BuLi} \, (2 \, \text{equiv}) \, \text{then} \, \text{DMF}\)
These reagents are typically used for hydrazone formation followed by anion generation and formylation. However, this sequence is less suited for the current conversion of a ketone to an aldehyde without additional steps.
i) \(1,3-\text{dithane}, \, {^n}\text{BuLi}\); ii) \(\text{HgSO}_4, \, \text{dil.} \, \text{H}_2\text{SO}_4\)
This set typically involves dithiane protection followed by hydrolysis to regenerate the carbonyl group. It doesn't directly convert a ketone to an aldehyde under the given conditions.
Thus, the correct sets of reagents that can perform the conversion are:
These options allow the conversion of a ketone to an aldehyde effectively.
The presence of unsaturation in an organic compound can be detected by
Which of the following boron compounds is used as a reducing agent in organic synthesis?
In elimination reaction of sec-Butyl trimethylammonium hydroxide, major product formed would be ________.
Find out the suitable products in the following Grignard reaction:
What will be the product in the following reaction ?