The relative order of rate constants in the following transformations are
To determine the relative order of rate constants in the given transformations, let's analyze the reactions shown in the image:
Considering these stereochemical factors and steric effects, the correct order of rate constants is \(K_2 > K_1\) and \(K_4 > K_3\).
Thus, the correct answer is: \(K_2 > K_1; K_4 >K_3\).
The correct order for the relative rate of esterification of I, II, and III with p-nitrobenzoyl chloride is

The Hammett plot for the following transformation is :

The correct sequence of processes involved in the following transformation is :

The correct order of basicity for the following compounds is

The intermediates involved in the following reaction are