All Exams Test series for 1 year @ ₹349 only
Question

The Hammett plot for the following transformation is :

The correct answer is

The question involves analyzing the Hammett plot for the given transformation. The Hammett equation is used to relate the reaction rates of a series of related compounds to the substituents present on the aromatic rings. It is represented as:

\[\log \left(\frac{k}{k_0}\right) = \sigma \rho\]

where \(k\) is the rate constant for a substituted compound, \(k_0\) is the rate constant for the unsubstituted compound, \(\sigma\) is the substituent constant specific for a given position, and \(\rho\) is the reaction constant.

For this transformation, we notice:

  • The reaction involves the change of a phenolic compound.
  • The substituents \(X\) affect the acidity and reactivity of the phenolic group.
  • Typically, electron-withdrawing groups increase the acidity, impacting the reaction rate.

The Hammett plot, therefore, shows the effect of substituents on the reaction rate. The correct Hammett plot for this transformation indicates a direct correlation between \(\log \left(\frac{k}{k_0}\right)\) and the substituent constants \(\sigma\). As the data is linear, it supports the use of the Hammett equation.

The correct answer is the plot showing a positive correlation with a slope reflecting the electron-withdrawing nature of the substituents enhancing the reaction rate.

Was this answer helpful?

Important Questions from Organic Reaction Mechanisms

  1. The correct order for the relative rate of esterification of I, II, and III with p-nitrobenzoyl chloride is 

  2. The correct sequence of processes involved in the following transformation is :

  3. The relative order of rate constants in the following transformations are

  4. The correct order of basicity for the following compounds is

  5. The intermediates involved in the following reaction are

Need Expert Advice?

Start Your Preparation with Prepp Mobile App

Download the app from Google Play & App Store
Download the app from Google Play & App Store
Prepp Mobile App