Acrylic fiber is primarily manufactured using the wet spinning process because the acrylic polymer exhibits poor thermal resistance. This means it degrades or decomposes at temperatures required for melt spinning.
Acrylic polymers tend to decompose rather than melt cleanly when heated. Attempting melt spinning would lead to polymer degradation, resulting in fiber breakage and poor fiber quality. Therefore, the poor thermal resistance of the acrylic polymer makes melt spinning unsuitable.
The wet spinning process bypasses the need for high melting temperatures. By dissolving the acrylic polymer in a solvent (like dimethylformamide or acrylonitrile), it can be spun into fibers at much lower, non-damaging temperatures. The resulting solution is extruded through spinnerets into an aqueous or chemical bath, causing the polymer to precipitate and form solid fibers. This avoids thermal degradation.
Conclusion: The choice of wet spinning for acrylic fiber production is directly dictated by the polymer's inherent poor thermal resistance.