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Question

In a certain process, the relation between pressure ($P$) and volume ($V$), for an ideal gas, is given by $PV^2 = \text{constant}$. If the initial temperature is $T_1$ and the final temperature is $T_2$; and the initial volume is $V_1$ and the final volume is $V_2$, then which one of the following is correct?

The correct answer is
$\frac{T_1}{T_2} = \frac{V_2}{V_1}$

Deriving the Temperature-Volume Relation for $PV^2 = \text{constant}$

We are given a process for an ideal gas where the relation between pressure ($P$) and volume ($V$) is $PV^2 = K$, where $K$ is a constant.

From the Ideal Gas Law, we know that for a fixed amount of gas ($n$), $PV = nRT$, where $R$ is the ideal gas constant and $T$ is the absolute temperature.

We can express pressure ($P$) from the Ideal Gas Law as: $P = \frac{nRT}{V}$

Now, substitute this expression for $P$ into the given process equation ($PV^2 = K$): $ \left(\frac{nRT}{V}\right) V^2 = K $ $ nRT V = K $

Since $n$ and $R$ are constants, we can rewrite the equation as: $ TV = \frac{K}{nR} $ Let $\frac{K}{nR} = \text{constant}'$. Therefore, the process follows the relation: $ TV = \text{constant}' $

Applying the Constant Relation to Initial and Final States

This means that the product of temperature and volume remains constant throughout the process. Applying this to the initial state (1) and the final state (2): $ T_1 V_1 = \text{constant}' $ $ T_2 V_2 = \text{constant}' $

Equating these two expressions: $ T_1 V_1 = T_2 V_2 $

To find the relationship between the temperature ratio and the volume ratio, rearrange the equation: $ \frac{T_1}{T_2} = \frac{V_2}{V_1} $

This result matches option C.

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Important Questions from Thermodynamics

  1. If the work done on the system or by the system· is zero, which one of the following statements for a gas kept at a certain volume is correct?

  2. A system that does NOT allow exchange of heat with its surrounding is called

  3. A system that does NOT allow exchange of heat with its surrounding is called

  4. For a certain reaction, ΔG θ = -45 kJ/mol and ΔH θ = -90 kJ/mol at 0 °C. What is the minimum temperature at which the reaction will become spontaneous, assuming that ΔH θ  and ΔS θ  are independent of temperature?

  5. Which of the following statements correctly describes the thermodynamic classification of entropy?
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