We are given a process for an ideal gas where the relation between pressure ($P$) and volume ($V$) is $PV^2 = K$, where $K$ is a constant.
From the Ideal Gas Law, we know that for a fixed amount of gas ($n$), $PV = nRT$, where $R$ is the ideal gas constant and $T$ is the absolute temperature.
We can express pressure ($P$) from the Ideal Gas Law as: $P = \frac{nRT}{V}$
Now, substitute this expression for $P$ into the given process equation ($PV^2 = K$): $ \left(\frac{nRT}{V}\right) V^2 = K $ $ nRT V = K $
Since $n$ and $R$ are constants, we can rewrite the equation as: $ TV = \frac{K}{nR} $ Let $\frac{K}{nR} = \text{constant}'$. Therefore, the process follows the relation: $ TV = \text{constant}' $
This means that the product of temperature and volume remains constant throughout the process. Applying this to the initial state (1) and the final state (2): $ T_1 V_1 = \text{constant}' $ $ T_2 V_2 = \text{constant}' $
Equating these two expressions: $ T_1 V_1 = T_2 V_2 $
To find the relationship between the temperature ratio and the volume ratio, rearrange the equation: $ \frac{T_1}{T_2} = \frac{V_2}{V_1} $
This result matches option C.
If the work done on the system or by the system· is zero, which one of the following statements for a gas kept at a certain volume is correct?
A system that does NOT allow exchange of heat with its surrounding is called
A system that does NOT allow exchange of heat with its surrounding is called
For a certain reaction, ΔG θ = -45 kJ/mol and ΔH θ = -90 kJ/mol at 0 °C. What is the minimum temperature at which the reaction will become spontaneous, assuming that ΔH θ and ΔS θ are independent of temperature?