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Question

Fill in the blank with the most appropriate option.

An element attains stability when it achieves ________ state.

This question was previously asked in
RRB ALP 2018 CBT 2 Fitter Question Paper (21-Jan-2019) (Shift 3)
The correct answer is

a duplet or octet

Understanding Atomic Stability and Electron Configuration

Atoms of elements strive to achieve a stable electronic configuration. This stability is typically achieved when the outermost electron shell contains a specific number of electrons, resembling the configuration of noble gases.

There are two primary stable configurations that elements aim for:

  • Duplet State: This occurs when the outermost electron shell contains 2 electrons. This configuration is similar to that of the noble gas Helium. Elements like Hydrogen and Lithium (when forming ions) achieve stability by having a duplet in their valence shell.
  • Octet State: This is a more common stable configuration where the outermost electron shell contains 8 electrons. This configuration is similar to noble gases like Neon, Argon, Krypton, etc. Most elements achieve stability by gaining, losing, or sharing electrons to have 8 electrons in their valence shell. This is known as the octet rule.

Elements achieve these stable states through chemical bonding, which involves the transfer or sharing of valence electrons. By reaching a duplet or octet configuration, the atom attains a lower energy state, making it stable and less reactive.

Analyzing the Given Options

Let's evaluate the provided options based on the concept of atomic stability:

  • Option 1: an only-duplet
    While some elements like Hydrogen and Helium achieve stability with a duplet, many other elements achieve stability with an octet. Therefore, stability is not limited to only a duplet.
  • Option 2: a duplet or octet
    This option correctly states that an element attains stability by achieving either a duplet (2 electrons) or an octet (8 electrons) in its outermost shell. This covers the stable configurations for most elements.
  • Option 3: an only-octet
    This is incorrect because lighter elements like Hydrogen and Helium achieve stability with a duplet, not an octet.
  • Option 4: a heptane
    Heptane ($\text{C}_7\text{H}_{16}$) is a hydrocarbon, which is a type of organic molecule. It is not related to the electronic configuration state that an element achieves for stability.

Based on the principles of chemical stability and electron configuration, an element attains stability when its outermost shell has either 2 electrons (duplet) or 8 electrons (octet), mimicking the stable configuration of noble gases.

Revision Table: Key Concepts

Concept Description Achieved By
Atomic Stability Tendency of atoms to achieve a low-energy, stable electron configuration. Achieving duplet or octet in the valence shell.
Duplet Rule Achieving 2 electrons in the outermost shell for stability. Elements like H, He.
Octet Rule Achieving 8 electrons in the outermost shell for stability. Most elements (Li to Ar and beyond, with exceptions for heavier elements).
Valence Shell The outermost electron shell of an atom. Contains valence electrons involved in bonding.

Additional Information on Stability and Electron Configuration

The drive for atoms to achieve a stable electron configuration explains why elements react and form chemical bonds. By losing, gaining, or sharing electrons, atoms can attain the same electron arrangement as a noble gas, which are known for their inertness (low reactivity).

  • Metals tend to lose valence electrons to achieve the stable configuration of the preceding noble gas.
  • Nonmetals tend to gain or share valence electrons to achieve the stable configuration of the nearest noble gas.

While the duplet and octet rules are fundamental for understanding the stability of many elements, especially those in the first few periods of the periodic table, there are exceptions for elements in later periods (e.g., those involving d-orbitals) which can accommodate more than 8 electrons in their valence shell (expanded octet).

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