Question
Consider the molecules / ions given below
$XeO_3$, $BF_4^-$, $I_3^-$, $SF_6$, $PCl_5$
The ratio of number of molecules having $sp^3d$ hybridisation to those having $sp^3$ hybridisation is ________
Hybridization Analysis of Given Species
We need to determine the hybridization of each molecule/ion: $XeO_3$, $BF_4^-$, $I_3^-$, $SF_6$, and $PCl_5$. This involves calculating the steric number (number of atoms bonded to the central atom + number of lone pairs on the central atom).
1. Determining Hybridization
- $XeO_3$: Central atom Xe. Steric Number = 3 (Xe-O bonds) + 1 (lone pair) = 4. Hybridization = $sp^3$.
- $BF_4^-$: Central atom B. Steric Number = 4 (B-F bonds) + 0 (lone pairs) = 4. Hybridization = $sp^3$.
- $I_3^-$: Central atom I. Steric Number = 2 (I-I bonds) + 3 (lone pairs) = 5. Hybridization = $sp^3d$.
- $SF_6$: Central atom S. Steric Number = 6 (S-F bonds) + 0 (lone pairs) = 6. Hybridization = $sp^3d^2$.
- $PCl_5$: Central atom P. Steric Number = 5 (P-Cl bonds) + 0 (lone pairs) = 5. Hybridization = $sp^3d$.
Hybridization Summary Table
| Molecule/Ion | Steric Number | Hybridization |
| $XeO_3$ | 4 | $sp^3$ |
| $BF_4^-$ | 4 | $sp^3$ |
| $I_3^-$ | 5 | $sp^3d$ |
| $SF_6$ | 6 | $sp^3d^2$ |
| $PCl_5$ | 5 | $sp^3d$ |
Calculating the Ratio
From the analysis above:
- Number of species with $sp^3d$ hybridization = 2 ($I_3^-$ and $PCl_5$).
- Number of species with $sp^3$ hybridization = 2 ($XeO_3$ and $BF_4^-$).
The required ratio is calculated as:
Ratio = (Number of $sp^3d$ species) / (Number of $sp^3$ species)
Using LaTeX notation:
Ratio = = 1
The ratio of the number of molecules having $sp^3d$ hybridization to those having $sp^3$ hybridization is 1.
Was this answer helpful?
Similar Questions
- A chromium complex with a formula $\text{CrCl}_3\cdot 6\text{H}_2\text{O}$ has a spin only magnetic moment value of $3.87 \text{ BM}$ and its solution conductivity corresponds to $1 : 2$ electrolyte. $2.75 \text{ g}$ of the complex solution was initially passed through a cation exchanger. The solution obtained after the process was reacted with excess of $\text{AgNO}_3$. The amount of $\text{AgCl}$ formed in the above process is _____ g. (Nearest integer)
[Given: Molar mass in $\text{g mol}^{-1}$ $\text{Cr} : 52; \text{Cl}: 35.5, \text{Ag}: 108, \text{O}: 16, \text{H}: 1$] - Consider the following reactions :
$\text{NaCl} + \text{K}_2\text{Cr}_2\text{O}_7 + \text{H}_2\text{SO}_4 \rightarrow \text{A} + \text{KHSO}_4 + \text{NaHSO}_4 + \text{H}_2\text{O}$
$\text{A} + \text{NaOH} \rightarrow \text{B} + \text{NaCl} + \text{H}_2\text{O}$
$\text{B} + \text{H}_2\text{SO}_4 + \text{H}_2\text{O}_2 \rightarrow \text{C} + \text{Na}_2\text{SO}_4 + \text{H}_2\text{O}$
In the product 'C', 'X' is the number of $\text{O}_2^{2-}$ units, 'Y' is the total number oxygen atoms present and 'Z' is the oxidation state of Cr. The value of X + Y + Z is ____________. - Identify the metal ions among $\text{Co}^{2+}, \text{Ni}^{2+}, \text{Fe}^{2+}, \text{V}^{3+}$ and $\text{Ti}^{2+}$ having a spin-only magnetic moment value more than $3.0\text{ BM}$. The sum of unpaired electrons present in the high spin octahedral complexes formed by those metal ions is __________.
The crystal field splitting energy of $[\text{Co(oxalate)}_3]^{3-}$ complex is '$n$' times that of the $[\text{Cr(oxalate)}_3]^{3-}$ complex. Here '$n$' is ___________. (Assume $\Delta_o >> P$)
- A metal complex with a formula $MCl_4.3NH_3$ is involved in $sp^3d^2$ hybridisation. It upon reaction with excess of $AgNO_3$ solution gives 'x' moles of AgCl. Consider 'x' is equal to the number of lone pairs of electron present in central atom of $BrF_5$. Then the number of geometrical isomers exhibited by the complex is ______
- In the leaching method, bauxite ore is digested with a concentrated solution of NaOH that produces 'X'. When $CO_2$ gas is passed through the aqueous solution of 'X', a hydrated compound 'Y' is precipitated. 'X' and 'Y' respectively are :-
- The total number of possible isomers for square- planar $[Pt(Cl)(NO_2)(NO_3)(SCN)]^{2–}$ is :-
- In $KO_2$, the nature of oxygen species and the oxidation state of oxygen atom are, respectively
The correct order of spin-only magnetic moments among the following is :
(Atomic number : Mn = 25, Co = 27, Ni= 28, Zn = 30)
- Biochemical Oxygen Demand (BOD) value can be a measure of water pollution caused by the organic matter. Which of the following statements is correct -
Important Questions from Inorganic Chemistry
- A chromium complex with a formula $\text{CrCl}_3\cdot 6\text{H}_2\text{O}$ has a spin only magnetic moment value of $3.87 \text{ BM}$ and its solution conductivity corresponds to $1 : 2$ electrolyte. $2.75 \text{ g}$ of the complex solution was initially passed through a cation exchanger. The solution obtained after the process was reacted with excess of $\text{AgNO}_3$. The amount of $\text{AgCl}$ formed in the above process is _____ g. (Nearest integer)
[Given: Molar mass in $\text{g mol}^{-1}$ $\text{Cr} : 52; \text{Cl}: 35.5, \text{Ag}: 108, \text{O}: 16, \text{H}: 1$] - Consider the following reactions :
$\text{NaCl} + \text{K}_2\text{Cr}_2\text{O}_7 + \text{H}_2\text{SO}_4 \rightarrow \text{A} + \text{KHSO}_4 + \text{NaHSO}_4 + \text{H}_2\text{O}$
$\text{A} + \text{NaOH} \rightarrow \text{B} + \text{NaCl} + \text{H}_2\text{O}$
$\text{B} + \text{H}_2\text{SO}_4 + \text{H}_2\text{O}_2 \rightarrow \text{C} + \text{Na}_2\text{SO}_4 + \text{H}_2\text{O}$
In the product 'C', 'X' is the number of $\text{O}_2^{2-}$ units, 'Y' is the total number oxygen atoms present and 'Z' is the oxidation state of Cr. The value of X + Y + Z is ____________. - Identify the metal ions among $\text{Co}^{2+}, \text{Ni}^{2+}, \text{Fe}^{2+}, \text{V}^{3+}$ and $\text{Ti}^{2+}$ having a spin-only magnetic moment value more than $3.0\text{ BM}$. The sum of unpaired electrons present in the high spin octahedral complexes formed by those metal ions is __________.
The crystal field splitting energy of $[\text{Co(oxalate)}_3]^{3-}$ complex is '$n$' times that of the $[\text{Cr(oxalate)}_3]^{3-}$ complex. Here '$n$' is ___________. (Assume $\Delta_o >> P$)
- Which of the following is the structure of pyrosulphuric acid?
Need Expert Advice?
More Questions from JEE Main
