P. Oil quenching
Q. Water quenching
R. Water quenching with agitation
S. Brine quenching
Quenching is a heat treatment process used to harden metals, primarily steels, by rapidly cooling them from a high temperature. The severity of quenching refers to the rate at which the material cools. A higher cooling rate generally leads to a greater degree of hardening but can also increase brittleness.
The cooling rate depends on the properties of the quenching medium (like thermal conductivity, specific heat, and viscosity) and the cooling conditions (like agitation).
Let's analyze the severity based on typical cooling rates:
Therefore, arranging these methods in terms of increasing severity (i.e., increasing cooling rate) gives:
Oil quenching (P) < Water quenching (Q) < Water quenching with agitation (R) < Brine quenching (S)
The correct order is P<Q<R<S.
The microstructures of a quenched steel tempered at three temperatures $T_1 < T_2 < T_3$ for a fixed time are schematically illustrated. The solid circles represent cementite particles in ferrite matrix; $\bar{r}_1, \bar{r}_2$ and $\bar{r}_3$ are average radii of cementite particles, and $V_1, V_2$ and $V_3$ are volume fractions of cementite at temperatures $T_1, T_2$ and $T_3$, respectively.

If the cementite in steel is more noble than ferrite, then which one of the three microstructures will have the highest corrosion rate when exposed to an aqueous solution of $3.5 \text{ wt.\% NaCl}$?