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Question

Which water-soluble pigment belonging to a phenolic group is present in pomegranate, eggplant, black carrots and red cabbage?

This question was previously asked in
SSC CGL 2023 (Tier-II) Paper 1 Previous Year Paper (26-Oct-2023) (Shift-1)
The correct answer is

Anthocyanins

Understanding Plant Pigments: Anthocyanins

The question asks about a specific type of water-soluble pigment that belongs to the phenolic group and is commonly found in vibrant fruits and vegetables like pomegranate, eggplant, black carrots, and red cabbage. Let's examine the properties of the pigments listed in the options.

Analyzing the Pigment Options

We need to identify the pigment that matches all the criteria: water-soluble, phenolic group, and present in the given sources.

  • Betalains: These are water-soluble pigments found in plants like beets, Swiss chard, and some cacti. They are nitrogen-containing compounds derived from tyrosine, but they do not belong to the phenolic group (specifically flavonoids).
  • Phycobilins: These are water-soluble pigments found in cyanobacteria and red algae. They are light-harvesting pigments linked to proteins (forming phycobiliproteins). They are not part of the phenolic group.
  • Phycoerythrin: This is a specific type of phycobilin, primarily found in red algae and some cyanobacteria. It absorbs green light and appears red. Like other phycobilins, it's water-soluble but not from the phenolic group.
  • Anthocyanins: These are water-soluble pigments that produce red, purple, blue, or black colors in fruits, vegetables, and flowers. They are part of the flavonoid group, which is a major class of phenolic compounds. Anthocyanins are widely found in sources mentioned in the question, such as pomegranate, eggplant peel, black carrots, red cabbage, berries, and grapes.

Why Anthocyanins Fit the Description

Based on the analysis:

  • Anthocyanins are explicitly described as water-soluble pigments.
  • They belong to the flavonoid class, which is a well-established subgroup of phenolic compounds.
  • Sources listed in the question (pomegranate, eggplant, black carrots, red cabbage) are well-known for their high content of anthocyanins, which are responsible for their characteristic colors.

Therefore, anthocyanins are the pigments that satisfy all the conditions mentioned in the question.

Summary of Pigment Properties

Pigment Type Water-Soluble? Belongs to Phenolic Group? Common Sources
Betalains Yes No Beets, some cacti
Phycobilins Yes No Cyanobacteria, red algae
Phycoerythrin Yes No Red algae, some cyanobacteria
Anthocyanins Yes Yes (as Flavonoids) Pomegranate, eggplant, black carrots, red cabbage, berries, grapes

Revision Table: Key Pigment Facts

Pigment Solubility Chemical Group Examples of Sources
Anthocyanins Water-soluble Phenolic (Flavonoid) Red cabbage, eggplant, pomegranate, berries
Betalains Water-soluble Nitrogenous (not phenolic) Beetroot, Swiss chard
Phycobilins Water-soluble Protein-bound chromophores (not phenolic) Red algae, cyanobacteria

Additional Information on Anthocyanins and Phenolics

Anthocyanins are glycosides of anthocyanidins. The difference lies in the presence of a sugar molecule. Anthocyanidins are the aglycones (without the sugar), while anthocyanins have sugar(s) attached. The phenolic nature comes from the multiple hydroxyl groups present on the aromatic rings in their chemical structure, which are characteristic of phenolic compounds.

The color of anthocyanins is influenced by pH. They tend to be red in acidic conditions, purple in neutral, and blue or green in alkaline conditions. This is why red cabbage can be used as a natural pH indicator.

Anthocyanins are known for their antioxidant properties and are being studied for potential health benefits.

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