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Question

Which one of the following statements about glass is not correct?

This question was previously asked in
NDA II 2019 GAT Previous Year Paper (17-Nov-2019)
The correct answer is

Soda glass is harder than pyrex glass

Understanding Glass Properties: Which Statement is Incorrect?

The question asks us to identify the statement that is not correct regarding the properties of glass. Glass is a fascinating material with unique characteristics that differentiate it from crystalline solids.

Analyzing Statements about Glass

Let's carefully examine each given statement:

  1. Glass is often said to be a super cooled liquid
  2. Glass has no definite melting point
  3. Soda glass is harder than pyrex glass
  4. Boron is present in pyrex glass

Now, let's evaluate the accuracy of each statement based on common scientific understanding of glass:

  • Statement 1: Glass is often said to be a super cooled liquid
    This statement is widely considered correct. Glass is an amorphous solid, meaning it lacks the long-range ordered structure of a crystalline solid. Its atoms or molecules are arranged in a disordered manner similar to a liquid, but it behaves mechanically like a solid. The term "supercooled liquid" reflects this structural characteristic and its behavior at high temperatures where it softens gradually rather than melting sharply.
  • Statement 2: Glass has no definite melting point
    This statement is correct. Unlike crystalline solids which melt at a specific, sharp melting temperature, amorphous solids like glass do not have a definite melting point. Instead, they gradually soften over a range of temperatures as they transition from a rigid state to a more fluid state. This temperature range is often referred to as the glass transition temperature.
  • Statement 3: Soda glass is harder than pyrex glass
    This statement is incorrect. Soda-lime glass, commonly known as soda glass, is the most prevalent type of glass used for windows and containers. It is relatively inexpensive but has limitations, such as lower resistance to thermal shock and chemical corrosion. Pyrex glass, which is a brand name for borosilicate glass, contains boron oxide. The addition of boron significantly changes the properties of the glass, making it more resistant to thermal expansion and contraction, and generally harder and more durable than soda-lime glass. Therefore, Pyrex glass is harder and more resistant than soda glass.
  • Statement 4: Boron is present in pyrex glass
    This statement is correct. As mentioned above, Pyrex is a type of borosilicate glass. The term "borosilicate" itself indicates the presence of boron oxides (typically boron trioxide, B2O3) as a key component along with silica (SiO2). Boron is added to reduce the coefficient of thermal expansion, which makes the glass highly resistant to changes in temperature and thermal shock.

Based on this analysis, the statement that is not correct is the one claiming that soda glass is harder than pyrex glass. In reality, pyrex glass is significantly harder and more durable than soda glass.

Summary of Glass Properties

Let's summarize the key properties discussed:

Property Description Soda Glass vs. Pyrex Glass
Structure Amorphous solid, often described as supercooled liquid Both are amorphous solids
Melting Point No definite melting point; softens over a range (glass transition) Both soften over a temperature range
Hardness/Durability Resistance to scratching, wear, and breakage Pyrex glass is generally harder and more durable than Soda glass
Composition (Key Additives) Silica (SiO2) is primary component Soda glass: Sodium oxide (Na2O), Calcium oxide (CaO)
Pyrex glass: Boron oxide (B2O3) is key additive

Conclusion on Incorrect Statement about Glass

The analysis confirms that the statement "Soda glass is harder than pyrex glass" is factually incorrect when comparing the typical properties of these two types of glass. Pyrex glass (borosilicate glass) is known for its superior hardness, durability, and thermal resistance compared to soda-lime glass (soda glass).

Revision Table: Key Glass Types and Properties

Glass Type Key Components (besides Silica) Common Uses Relative Hardness/Durability Thermal Properties
Soda-Lime Glass (Soda Glass) Sodium Oxide (soda), Calcium Oxide (lime) Windows, Bottles, Jars Lower Lower thermal shock resistance
Borosilicate Glass (Pyrex Glass) Boron Oxide Labware, Cookware, Telescope mirrors Higher High thermal shock resistance (low thermal expansion)

Additional Information on Glass Types

Beyond soda-lime and borosilicate glass, other types of glass exist, each with specialized properties based on their composition:

  • Lead Glass: Contains lead oxide, increasing refractive index (for crystalware) and density (for radiation shielding). It is softer than soda-lime glass.
  • Aluminosilicate Glass: Contains aluminum oxide, used in applications requiring high strength and scratch resistance, such as smartphone screens.
  • Fused Quartz/Silica Glass: Made almost entirely of silica, offering very high thermal shock resistance and transmission of UV light, used in scientific equipment and fiber optics.

Understanding the composition and resulting properties of different glass types is crucial in material science and various applications.

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