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Question

Which one of the following is called ‘syngas’?

This question was previously asked in
NDA I 2018 GAT Previous Year Paper (22-Apr-2018)
The correct answer is

CO(g) + H 2(g)

Understanding Syngas Composition

Syngas, short for synthesis gas, is an important industrial fuel gas mixture. It is primarily composed of carbon monoxide (CO) and hydrogen (H<sub>2</sub>).

Syngas is produced from various carbonaceous materials, such as coal, natural gas, biomass, or even plastic waste, through processes like gasification or steam reforming. The exact ratio of CO to H<sub>2</sub> can vary depending on the feedstock and the production process used.

Analyzing the Options for Syngas

Let's examine each option provided to identify which one correctly represents syngas:

  • Option 1: <p>C(s) + H <sub>2</sub>O(g)</p>

    This represents solid carbon reacting with steam (water vapor). This is one of the reactions used to produce syngas (the water-gas reaction), but it shows the reactants, not the syngas product itself.
  • Option 2: <p>CO(g) + H <sub>2</sub>O(g)</p>

    This shows carbon monoxide mixed with water vapor. While CO is a component of syngas, water vapor is not considered a primary component of the syngas product itself, although it can be present as an impurity or reactant in related processes.
  • Option 3: <p>CO(g) + H <sub>2</sub>(g)</p>

    This mixture of gaseous carbon monoxide (CO) and gaseous hydrogen (H<sub>2</sub>) is the standard definition of syngas.
  • Option 4: <p>NO <sub>2</sub>(g) + H <sub>2</sub>(g)</p>

    This mixture contains nitrogen dioxide (NO<sub>2</sub>) and hydrogen (H<sub>2</sub>). Nitrogen dioxide is a different compound altogether and is not a component of syngas.

Based on the definition and common understanding of syngas, the mixture of carbon monoxide and hydrogen gas is correctly identified as syngas.

Conclusion on Syngas Identity

Therefore, the option that correctly identifies syngas is the one representing the mixture of carbon monoxide and hydrogen gas.


Revision Table: Syngas Components

Let's summarize the options and their relation to syngas.

Option Composition Is it Syngas? Reasoning
1 C(s) + H<sub>2</sub>O(g) No Reactants for syngas production (Water-gas reaction)
2 CO(g) + H<sub>2</sub>O(g) No CO + Water vapor; water vapor is not the primary H<sub>2</sub> component of syngas
3 CO(g) + H<sub>2</sub>(g) Yes Standard definition of Syngas
4 NO<sub>2</sub>(g) + H<sub>2</sub>(g) No Contains NO<sub>2</sub>, which is not part of syngas


Additional Information on Syngas

Syngas is a crucial intermediate product in the chemical industry. Its name "synthesis gas" comes from its use as a building block (synthesizing agent) for producing various chemicals and fuels. Some key uses and facts about syngas include:

  • Methanol Production: Syngas is a primary feedstock for the synthesis of methanol (CH<sub>3</sub>OH). The reaction is <p>\(\text{CO(g)} + 2\text{H}_2\text{(g)} \rightleftharpoons \text{CH}_3\text{OH(g)}\)</p>.
  • Fischer-Tropsch Process: Syngas can be converted into synthetic liquid fuels (like gasoline and diesel) and waxes through the Fischer-Tropsch process. This process involves complex reactions where CO and H<sub>2</sub> react over a catalyst to form hydrocarbons.
  • Hydrogen Production: Syngas is often used to produce pure hydrogen through the water-gas shift reaction (<p>\(\text{CO(g)} + \text{H}_2\text{O(g)} \rightleftharpoons \text{CO}_2\text{(g)} + \text{H}_2\text{(g)}\)</p>), followed by separation.
  • Fuel: Syngas itself can be burned as a fuel gas for power generation or industrial heating. However, its lower heating value compared to natural gas makes it less desirable for some applications unless purification steps are taken.
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