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Question

Which of the following acid is used in car batteries?

This question was previously asked in
UPSSSC PET 2022 Question Paper (16-Oct-2022) (Shift 2)
The correct answer is Sulphuric acid

Acid Used in Car Batteries: Detailed Explanation

Car batteries, commonly known as lead-acid batteries, require a specific type of acid to function as an electrolyte. The electrolyte facilitates the chemical reactions needed to store and release electrical energy. Let's examine the options provided to understand which acid is used and why.

Understanding Battery Electrolytes

The electrolyte in a lead-acid battery is a mixture of sulfuric acid and water. This mixture allows ions to move between the positive and negative plates (lead dioxide and spongy lead, respectively) during the charge and discharge cycles.

Analysis of Acid Options

  • Sulphuric acid: This is the correct answer. Sulfuric acid ($H_2SO_4$) is a strong acid that dissociates readily in water, providing the necessary ions ($H^+$ and $SO_4^{2-}$) for the electrochemical reactions in a car battery. Its properties make it ideal for the demanding environment within a battery, balancing conductivity, stability, and cost-effectiveness.
  • Acetic acid: Commonly found in vinegar, acetic acid ($CH_3COOH$) is a weak acid. It is not suitable for car batteries because it lacks the conductivity required for efficient energy transfer and can lead to undesirable side reactions and corrosion of the battery components.
  • Hydrochloric acid: Hydrochloric acid ($HCl$) is a strong acid, but it is not used in car batteries. If used, it could react with the lead plates to form lead chloride ($PbCl_2$), which is an insulator and would prevent the battery from functioning. It can also produce dangerous chlorine gas under certain conditions.
  • Nitric acid: Nitric acid ($HNO_3$) is a strong oxidizing acid. While it can conduct electricity, it is highly corrosive and tends to react aggressively with the materials used in battery plates, leading to rapid degradation and potential failure. It is not stable enough for long-term use as a battery electrolyte.

Acid Comparison for Battery Use

Here's a comparison of the acids mentioned:

Acid Properties and Battery Suitability
Acid Name Chemical Formula Acid Strength Suitability for Car Batteries Primary Use/Reason
Sulphuric acid $H_2SO_4$ Strong Suitable Electrolyte in lead-acid batteries
Acetic acid $CH_3COOH$ Weak Not Suitable Food (vinegar), cleaning
Hydrochloric acid $HCl$ Strong Not Suitable Industrial cleaning, chemical synthesis
Nitric acid $HNO_3$ Strong Not Suitable Fertilizers, explosives, oxidizing agent

Conclusion

Based on its chemical properties and performance in electrochemical applications, sulphuric acid is the acid universally used in the electrolyte of conventional car batteries (lead-acid type).

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