The major product formed in the following reaction is

The given reaction involves the nitration of a benzene derivative. In this reaction, concentrated nitric acid (HNO3) is used as the nitrating agent, usually in the presence of a catalyst such as sulfuric acid, under moderate temperature (30°C).
The starting compound is a benzene ring with two carboxylic acid groups (COOH) in the meta positions relative to each other. In electrophilic aromatic substitution reactions, such as nitration, carboxyl groups are deactivating and meta-directing due to their electron-withdrawing nature.
Let's analyze the positions where the nitro group (NO2) might add:
Based on these points, the major product will most likely have a nitro group added to the position which is para to one COOH and ortho/meta to the other COOH, respecting the meta-directing effect of the COOH groups.
The correct structure according to the given options is:

This product aligns with the prediction given the meta-directing influence of the carboxylic acid groups.
The compound, which upon mono-nitration using a mixture of HNO$_3$ and H$_2$SO$_4$, does NOT give the meta-isomer as the major product, is
Identify the CORRECT product in the following reaction:
The total number of tautomers for the following molecule (including the structure provided below) is ____________
