All Exams Test series for 1 year @ ₹349 only
Question

The geometry of IF7 is :

This question was previously asked in
MH SET 2021 Paper 2 Mathematical Science Question Paper (26-Sep-2021)
The correct answer is

pentagonal bipyramidal

Iodine heptafluoride is the classic AX7 molecule of VSEPR theory. Iodine has seven valence electrons and each of the seven fluorine atoms forms one I–F bond, so the iodine carries seven bonding pairs and no lone pair.

Step 1 — Electron domains on I: 7 bonding pairs + 0 lone pairs = 7. Step 2 — Seven equivalent domains are best arranged as a pentagonal bipyramid: five fluorines in an equatorial pentagon and two axial fluorines, point group D5h. Electron diffraction confirms this shape, with the equatorial ring slightly puckered by fluxional motion.

A capped octahedron is the other common seven-coordinate polyhedron, found when six domains are arranged octahedrally with a seventh capping a face (as with the stereochemically active lone pair in XeF6); IF7 has no lone pair to cause this. A cube needs eight vertices and a trigonal prism only six, so neither fits a seven-coordinate centre.

pentagonal bipyramidal option is correct.

Was this answer helpful?

Similar Questions

  1. The hybridization for the complex ion [FeF6]3- and [Fe(CN)6]3- is :

  2. Which of the following diatomic molecules is paramagnetic ?

  3. Size of the d orbitals for Si, P, S and Cl follow the order :

  4. The molecules P4 and CH4 exhibit the same :

  5. The bond order for O2 and the hypothetical molecules N2- and O2+ will follow the trend :

  6. According to CFT, Ni2+ can have two unpaired electrons in :

  7. Which of the following complexes will NOT exhibit ideal octahedral geometry ?

  8. The carbonyl stretching frequency (νCO) for the complexes (i) [Co(CO)4]- (ii) [Ni(CO)4] and (iii) [Fe(CO)4]2- will follow the trend :

  9. The spin only magnetic moment for the complex Hg[Co(SCN)4] is :

  10. The molecular formula for sodium bis (thiosulphato) argentate (I) is :


Important Questions from Mixed Topic (MH-SET)

  1. .................... is a client server application that identifies each host on the internet with a unique user-friendly name.

  2. Every OS has a ................ or .......... which primarily resides in the main memory of the computer to perform some of the basic functions of the OS.

    (i) Kernel

    (ii) Interface

    (iii) Nucleus

    (iv) Compiler

    Codes:

  3. Which of the following are referred to as low level language?

    (i) Machine language

    (ii) Assembly language

    (iii) High level language

    (iv) Natural language

    Codes:

  4. Match the following:

    List IList II
    (a) New York Public Library(i) Shelv AR
    (b) Miami University Augmented Research Group(ii) Smart library
    (c) Oula University Library(iii) Wolf Walk
    (d) North Carolina State University(iv) Find the future

    Codes:

  5. Which part of the QR code represents the encoded data?

Need Expert Advice?
Upcoming Exams
CTET
December 12, 2026
CBSE UGC NET
December 14, 2026
CSIR UGC NET
December 19, 2026
Test Series
MH-SET img
Teaching
MAHA TAIT Mock Test Series (New)
58 Tests 1 Tests Free
3854 Attempts
4.9(108)
English, Hindi, Marathi
More Questions from MH-SET

Start Your Preparation with Prepp Mobile App

Download the app from Google Play & App Store
Download the app from Google Play & App Store
Prepp Mobile App