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Question

The γ-ray source used in 57Fe Mössbauer spectroscopy is :

This question was previously asked in
MH SET 2024 Paper 2 Computer Science and Applications Question Paper (07-Apr-2024)
The correct answer is

57Co

Mössbauer spectroscopy needs a radioactive source that populates an excited level of the same nucleus being studied, so that the emitted γ-ray can be resonantly absorbed by the sample.

57Co (half-life about 271 days) decays by electron capture to an excited state of 57Fe at 136 keV, which cascades to the 14.4 keV level; the 14.4 keV transition to the ground state is the Mössbauer γ-ray used for iron.

119mSn is the source for 119Sn Mössbauer spectroscopy and 121mSn is the source for 121Sb Mössbauer spectroscopy, while a technetium isotope cannot populate an excited state of iron.

So the source for 57Fe Mössbauer work is cobalt-57, usually diffused into a rhodium matrix.

Hence, 57Co.

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